首页> 外文会议>International Symposium on Chemical and Biological Sensors and Analytical Methods II, 2001 >AMPEROMETRIC AMMONIA SENSOR USING POLYPYRROLE AND SUBSTITUTED POLYPYRROLE WITH DIFFERENT DOPANTS
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AMPEROMETRIC AMMONIA SENSOR USING POLYPYRROLE AND SUBSTITUTED POLYPYRROLE WITH DIFFERENT DOPANTS

机译:使用多吡咯和取代的多吡咯的安培氨传感器

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The aim of the present work remains in the improvement of amperometric ammonia analysis, using a polypyrrole film doped with DBSA anions. This large amphiphilic dopant promotes changes on the polymeric film presenting a more accentuated response and extending the linear response over a wide range of concentrations, when compare with films doped with small inorganic anions, such as chloride. The substituted pyrrole monomers, as N-methyl-pyrrole, was also used with the aim of investigating the role played by acid hydrogen present in polypyrrole. The response of the sensor was followed by EQCM and Raman Spectroscopy experiments as tools to elucidate the mechanism of ammonia detection.
机译:本工作的目的仍然是使用掺杂有DBSA阴离子的聚吡咯膜来改进安培氨法分析。与掺杂有少量无机阴离子(如氯离子)的薄膜相比,这种大的两亲性掺杂剂可促进聚合物薄膜的变化,从而在更大的浓度范围内呈现出更突出的响应并扩展线性响应。为了研究聚吡咯中存在的酸氢所起的作用,还使用了取代的吡咯单体(如N-甲基-吡咯)。通过EQCM和拉曼光谱实验跟踪传感器的响应,以阐明氨气检测的机理。

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