Electrochemical Synthesis of C_(60)C(CN)_2 with Stronger Electron-accepting Ability

机译：电化学合成具有较强电子接受能力的C_（60）C（CN）_2

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摘要

A C_(60) monocyclic adduct C_(60)C(CN)_2 was prepared by the reaction of BrCH(CN)_2 with C_(60)~(2-) anions which were produced by the electrochemical reduction of C_(60). The reduction and the reaction processes were monitored by in situ NIR spectroscopy. The cyclic voltammogram indicates that it has stronger electron-accepting ability than C_(60).

机译：通过BrCH（CN）_2与C_（60）〜（2-）阴离子的反应制备C_（60）单环加合物C_（60）C（CN）_2，该阴离子通过电化学还原C_（60）。通过原位近红外光谱监测还原和反应过程。循环伏安图表明它比C_（60）具有更强的电子接受能力。

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来源
《International Symposium on Fullerenes 2000 Vol.8: Electrochemistry and Photochemistry, May 14-18, 2000, Toronto》|2000年|p.121-130|共10页
会议地点 Toronto(CA);Toronto(CA)
作者
Louzhen Fan; Yongfang Li; Juhua Xu; Yuliang Li; Daoben Zhu;
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作者单位

Department of Chemistry, Beijing Normal University, Beijing, 100875, P. R. China;

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原文格式 PDF
正文语种 eng
中图分类无线电电子学、电信技术;
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Electrochemical Synthesis of C_(60)C(CN)_2 with Stronger Electron-accepting Ability

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