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A THERMODYNAMIC ANALYSIS FOR DETERMINING CONTACT ANGLE AND CONTACT ANGLE HYSTERESIS

机译:确定接触角和接触角滞后的热力学分析

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摘要

@@Contact Angle (CA) and CA hysteresis (CAH) are significant to characterize wettable property of a surface. In this study, a free energy thermodynamiC approach is used to analysis the wettable behavior of a droplet on microtextured superhydrophobic surface, regularly microsphere and micropillar geometric distribution mode. We demonstrate that the predicted the equilibrium contact angle and CAH are consistent with the calculations of Wenzel's and Cassie's theories and also experimental results. Apparently, the thermodynamic approach based on the first principle and free energy minimization presented simplifies and make clear some confusion in the wettable behavior. Moreover, it provides potential guiding for designing stable superhydrophobic surfaces.
机译:接触角(CA)和CA滞后(CAH)对于表征表面的可湿性至关重要。在这项研究中,使用自由能热动力学方法来分析微结构化超疏水表面,规则微球和微柱几何分布模式下液滴的可湿性。我们证明了预测的平衡接触角和CAH与Wenzel和Cassie理论的计算以及实验结果是一致的。显然,基于第一原理和所提出的自由能最小化的热力学方法简化了可湿性行为,并弄清了一些混淆。而且,它为设计稳定的超疏水表面提供了潜在的指导。

著录项

  • 来源
  • 会议地点 Xiamen(CN);Xiamen(CN)
  • 作者单位

    State Key Laboratory of Polymer Physics and Chemistry Institute of Chemistry,Chinese Academy of Sciences,P.R.China;

    State Key Laboratory of Polymer Physics and Chemistry Institute of Chemistry,Chinese Academy of Sciences,P.R.China;

    State Key Laboratory of Polymer Physics and Chemistry Institute of Chemistry,Chinese Academy of Sciences,P.R.China;

    State Key Laboratory of Polymer Physics and Chemistry Institute of Chemistry,Chinese Academy of Sciences,P.R.China;

  • 会议组织
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 高分子化学(高聚物);
  • 关键词

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