IN SITU STUDIES OF CORROSION USING X-RAY ABSORPTION NEAR SPECTROSCOPY (XANES)

机译：利用X射线近吸收光谱法（XANES）进行腐蚀的原位研究。

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Applications of x-ray absorption near-edge spectroscopy (XANES) and the design of cells for in situ corrosion studies are reviewed. Passive films studies require very thin metal or alloy layers be used having a thickness of the order of the films formed because of penetration of the x-ray beam into the metal substrate. The depth of penetration in water also limits the thickness of solutions that can be used because of water reduces the x-ray intensity. Solution thickness must also be limited in studies of conversion layer formation studies because the masking of the Cr in solution. Illustrative examples are taken from the anodic behavior of Al-Cr alloys, the growth of passive films on Fe and stainless steels, and the formation of chromate conversion layers on Al.

机译：综述了X射线吸收近边缘光谱法（XANES）的应用以及用于原位腐蚀研究的电池设计。被动薄膜研究要求使用非常薄的金属或合金层，因为X射线束会穿透到金属基材中，因此其厚度约为所形成薄膜的厚度。水中的渗透深度也限制了可以使用的溶液的厚度，因为水会降低X射线强度。在转化层形成研究中，溶液厚度也必须受到限制，因为溶液中Cr的掩蔽。 Al-Cr合金的阳极行为，Fe和不锈钢上钝化膜的生长以及Al上铬酸盐转化层的形成是示例性的例子。

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《International Symposium on State-of-the-Art Application of Surface and Interface Analysis Methods to Environmental Material Interactions: in Honor of James E.Castle's 65th Year, Mar 26-27, 2001, Washington D.C.》|2001年|p.271-281|共11页
会议地点 Washington DC(US)
作者
H.S. Isaacs; P. Schmuki; S. Virtanen;
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Materials Science Division, Energy Sciences and Technology Department, Brookhaven National Laboratory, Upton, NY 11973, USA;

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原文格式 PDF
正文语种 eng
中图分类一般工业技术;
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8. In situ studies of corrosion using x-ray absorption near spectroscopy (xanes) [R] . Isaacs, H. S., Schmuki, P., Virtanen, S. 2001

机译：使用光谱附近的X射线吸收进行腐蚀的原位研究（xanes）

IN SITU STUDIES OF CORROSION USING X-RAY ABSORPTION NEAR SPECTROSCOPY (XANES)

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