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Applications of Electron Beam in Nanotechnology

机译:电子束在纳米技术中的应用

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The use of radiation technique to process nanostructured materials or to produce nanostructured materials have been shown technically superior as alternative and viable techniques for further commercial exploitation. Research on radiation processing of nanocomposites have been initiated at the Radiation Processing Technology Division of MINT in the past three years. The main focus of this research is to utilize indigenous natural polymer for production of nanocomposites material. Natural rubber/clay composites and thermoplastic natural rubber/clay composites are the important materials that under studied. The natural rubber used in this work is of grade SMRL (Standard Malaysian Rubber) and the clay used was sodium montmorillonite modified with various types of cationic surfactants in order to make the galleries hydrophobic and thus more compatible with the elastomer. The natural rubber/clay nanocomposites were prepared by melt mixing. The compound was then irradiated using electron beam at optimum dose of 250 kGy. X-ray diffraction results indicated intercalation of the natural rubber into silicate interlayer. Upon irradiation at 250 kGy, the tensile strength of the NR/Na-MMT nanocomposites constantly reduced slightly with increasing clay loading, whereas the tensile strengths of NR/DDA-MMT and NR/ODA-MMT increases to optimum levels, 12.1 MPa and 9.5 MPa respectively at 3 phr clay contents. On the other hand, the elongation of NR/DDA-MMT nanocomposites is less affected with increasing clay content up to 3 phr.
机译:作为替代和可行的技术,辐射技术用于处理纳米结构材料或生产纳米结构材料已被证明在技术上具有优越性,可用于进一步的商业开发。在过去三年中,MINT的辐射处理技术部已开始对纳米复合材料的辐射处理进行研究。这项研究的主要重点是利用天然天然聚合物生产纳米复合材料。天然橡胶/粘土复合材料和热塑性天然橡胶/粘土复合材料是正在研究的重要材料。在这项工作中使用的天然橡胶是SMRL(马来西亚标准橡胶)级,使用的粘土是蒙脱土钠,并用各种类型的阳离子表面活性剂改性,以使画廊疏水,从而与弹性体更加相容。通过熔融混合制备天然橡胶/粘土纳米复合材料。然后使用电子束以250 kGy的最佳剂量辐照该化合物。 X射线衍射结果表明天然橡胶嵌入到硅酸盐中间层中。在250 kGy辐射下,随着粘土含量的增加,NR / Na-MMT纳米复合材料的抗张强度不断降低,而NR / DDA-MMT和NR / ODA-MMT的抗张强度增加到最佳水平,分别为12.1 MPa和9.5。分别在3 phr粘土含量下为MPa。另一方面,NR / DDA-MMT纳米复合材料的伸长率随着黏土含量增加至3 phr而受到的影响较小。

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