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首页> 外文会议>Large scale energy storage for smart grid applications >Electron Spin Resonance Investigation of the Effects of Vanadium Ions in Ion Exchange Membranes for uses in Vanadium Redox Flow Batteries
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Electron Spin Resonance Investigation of the Effects of Vanadium Ions in Ion Exchange Membranes for uses in Vanadium Redox Flow Batteries

机译：电子自旋共振研究钒在氧化还原液流电池中使用的离子交换膜中的作用

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摘要

Electron Spin Resonance (ESR) was used to characterize the effects of the vanadyl ion in Nation 117. The ESR signal of a tempone spin probe was used as a qualitative standard to compare the signal intensity of the spin probe imbibed in the membrane with the intensity of the vanadium signal in the membrane. Initial measurements of vanadium crossover were recorded by monitoring vanadyl ion concentration increase in a blank solution flowed on one side of the battery apparatus as vanadyl ion solution was flowed simultaneously on the opposite side.
机译：电子自旋共振（ESR）用来表征117号国家中钒氧离子的作用。以tempone自旋探针的ESR信号为定性标准，比较膜中吸收的自旋探针的信号强度与强度膜中钒信号的变化通过监测在电池装置的一侧上流动的空白溶液中钒离子溶液同时在另一侧流动时钒离子浓度的增加，来记录钒穿越的初始测量值。

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  • 会议地点 Boston MA(US)
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    Jamie S. Lawton; Doug Aaron; Zhijiang Tang; Tom Zawodzinski;

  • 作者单位

    Department of Chemical and Biomolecular Engineering, University of Tennessee at Knoxville, Knoxville, Tennessee 37996, USA;

    Department of Chemical and Biomolecular Engineering, University of Tennessee at Knoxville, Knoxville, Tennessee 37996, USA;

    Department of Chemical and Biomolecular Engineering, University of Tennessee at Knoxville, Knoxville, Tennessee 37996, USA;

    Department of Chemical and Biomolecular Engineering, University of Tennessee at Knoxville, Knoxville, Tennessee 37996, USA,Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA;

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