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Application of extractive FTIR (fourier transform infrared) spectroscopy for speciated measurement of uncontrolled emissions at an asphalt coating process: sampling and analysis challenges at a complex emission source

机译:萃取式FTIR(傅里叶变换红外)光谱技术在沥青涂层过程中特定测量不受控制的排放量:复杂排放源的采样和分析挑战

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Uncontrolled emissions from an asphalt coating operation were performed using Extractive FTIR spectroscopy. Signifiant sampling and spectral analysis challenges were encountered due to the complex effluent composition that included several HAPs and numberous volatile and semi-volatile organics. The semi-volatile species included high molecular weight aliphatic hydrocarbons that could condense in the heated sampling system and continue to be detected at low levels for an extended period. Sampling system contamination was minimized by limiting samping time and purging between test runs. On-site QA/QC procedures included local, system, and dynamic matrix spiking calibrations with Methanol, 1,3-Butadiene, and p-Xylene.
机译:使用萃取FTIR光谱仪进行了沥青涂层操作的不受控制的排放。由于复杂的出水成分(包括几种HAP和大量的挥发性和半挥发性有机物),因此面临着巨大的采样和光谱分析挑战。半挥发性物质包括高分子量脂族烃,它们可能在加热的采样系统中凝结,并在很长一段时间内继续以低水平被检测到。通过限制采样时间和两次测试之间的吹扫,将采样系统的污染降至最低。现场QA / QC程序包括使用甲醇,1,3-丁二烯和对二甲苯进行的本地,系统和动态基质加标校准。

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