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Application of extractive FTIR (fourier transform infrared) spectroscopy for speciated measurement of uncontrolled emissions at an asphalt coating process: sampling and analysis challenges at a complex emission source

机译:提取FTIR(傅立叶变换红外)光谱在沥青涂层过程中不受控制排放规格测量的应用:复杂排放源的取样和分析挑战

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Uncontrolled emissions from an asphalt coating operation were performed using Extractive FTIR spectroscopy. Signifiant sampling and spectral analysis challenges were encountered due to the complex effluent composition that included several HAPs and numberous volatile and semi-volatile organics. The semi-volatile species included high molecular weight aliphatic hydrocarbons that could condense in the heated sampling system and continue to be detected at low levels for an extended period. Sampling system contamination was minimized by limiting samping time and purging between test runs. On-site QA/QC procedures included local, system, and dynamic matrix spiking calibrations with Methanol, 1,3-Butadiene, and p-Xylene.
机译:使用萃取的FTIR光谱进行沥青涂层操作的不受控制的排放。 由于包括若干HAP和挥发性和半挥发性有机物的复杂的流出物组合物,因此遇到了引光的取样和光谱分析挑战。 半挥发性物种包括高分子量脂族烃,其可以在加热的采样系统中凝结,并继续在低水平下在延长的时间内检测到。 通过限制幅度幅度和试验之间的吹扫,最小化采样系统污染。 现场QA / QC程序包括局部,系统和动态矩阵用甲醇,1,3-丁二烯和对二甲苯的校正校准。

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