The electrochemical characterization of Zr_(1-x)Ti_x ranging between 0.1 and 0.4, was carried out in order to determine its possible application as negative electrode in nickel/metal-hydride rechangable batteries. Electrodes of this alloy were tested along chanrge and discharge cycles. The effects of charge velocity and temperature on the electrode capacity were also investigated. The results obtained show that: i) the Zr rich alloy electrodes exhibit the highest discharge capacities, attaining up to 160 mAh/g, and the best perfrmances during fast charge-discharge cycling; ii) the discharge capacity increases with temperature; iii) potential cycling at 1 mV/s decrease the time of activation of the alloy electrode as compared with that observed during galvanostatic cycling.
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机译:为了确定Zr_(1-x)Ti_x在镍/金属氢化物可换电池中作为负极的可能应用,对Zr_(1-x)Ti_x进行了电化学表征。该合金的电极沿充放电循环进行了测试。还研究了充电速度和温度对电极容量的影响。得到的结果表明:i)富Zr合金电极在快速充放电循环中表现出最高的放电容量,达到160 mAh / g,并且具有最佳的性能。 ii)放电容量随温度增加; iii)与在恒电流循环期间观察到的相比,以1 mV / s的电位循环减少了合金电极的激活时间。
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