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Investigations on Steam Reforming Catalysts for Diesel Fuel

机译:柴油燃料蒸汽重整催化剂的研究

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Fuel cells can be applied as highly efficient auxiliary power units when being supplied with hydrogen. Since there is no adequate hydrogen infrastructure available yet, liquid fuels like Diesel can serve as a hydrogen source when it is converted into a hydrogen-rich gas in a reforming process fuel conversion by steam reforming (SR) promises the highest hydrogen yield in comparison to autothermal reforming (ATR) or catalytic partial oxidation (CPO). In the presented work several SR catalysts were tested at 750 °C and a steam to carbon ratio of 4, using a Diesel reference fuel with a sulphur content of ζ_(s)<10 ppm. Steam reforming was studied for varying Gas Hourly Space Velocities (GHSV) with respect to the hydrogen yield. In addition, studies of catalyst deactivation in the presence of sulphur and the catalysts' ability to regenerate by carbon combustion with air were completed. Some catalysts show promising results, while we identify one catalyst that has a high potential for a continuous Diesel SR application. Closing the presentation, we discuss the reproducibility of the results, and we give recommendations for further investigations.
机译:当供应氢气时,燃料电池可作为高效辅助动力单元施加。由于没有足够的氢基础设施可用,液体燃料如柴油可以用作氢气源,当它通过蒸汽重整(SR)通过蒸汽重整而转化为富含氢气的燃料转换(SR),相当于最高的氢屈服自热改性(ATR)或催化部分氧化(CPO)。在所提出的作品中,使用具有柴油参考燃料的含有柴油含量的χ_(S)<10ppm的硫含量,在750℃并蒸汽与碳比为4。研究了蒸汽重整,用于相对于氢屈服的变化气体空间速度(GHSV)。此外,完成了硫磺和催化剂通过碳燃烧与空气的催化剂去激活的研究。一些催化剂表明了有希望的结果,而我们鉴定了一种具有高潜力对于连续柴油SR应用的催化剂的催化剂。关闭演示文稿,我们讨论了结果的再现性,我们提出了进一步调查的建议。

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