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Potential for the Simultaneous Capture and Utilization of CO2 Using Desalination Reject Brine: Amine Solvent Selection and Evaluation

机译:使用海水淡化抑制盐水同时捕获和利用二氧化碳:胺溶剂选择和评价

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In the present study, the potential for the use of different amines with desalination brines for the simultaneous capture and conversion of CO2 into solid bicarbonates was evaluated. The focus of this work was to find the most suitable amine solvent for this proposed process. Various classes of amine solvents such as primary, secondary, tertiary and cyclic amines were identified and evaluated using the following parameters: Precipitate yield, CO2 capacity and Sodium conversion. The results showed that bicarbonate salts of good purity can be synthesized by bubbling simulated flue gas into amine/brine solution Also the sterically hindered amine, AMP, was found to be the best amine for the process due to its high precipitate yield and sodium conversion. Sodium removal above 80% was obtained when AMP was used. For all amines tested, the precipitated bicarbonate had a purity of over 95% while the CO2 capacity varied, with Piperazine having the highest. The obtained results demonstrate that the proposed process is a promising technology for the simultaneous capture and utilization of CO2 using desalination reject brine.
机译:在本研究中,评价将不同胺用于同时捕获和转化为固体碳酸氢盐的脱盐盐水中的不同胺的可能性。这项工作的重点是为此提出的过程找到最合适的胺溶剂。使用以下参数鉴定和评估各种类胺溶剂,例如初级,二级,叔胺和环状胺:沉淀产率,CO 2容量和钠转化。结果表明,通过将模拟烟气吸入胺/盐水溶液,可以将模拟的烟气溶解为胺/盐水溶液的碳酸氢盐盐,发现该过程是该方法的最佳胺,因为其高沉淀收率和钠转化率。当使用AMP时,获得了80%以上的钠去除。对于所有测试的胺,沉淀的碳酸氢盐的纯度超过95%,而二氧化碳容量变化,具有最高的哌嗪。所得结果表明,所提出的方法是使用脱盐拒绝盐水同时捕获和利用二氧化碳的有前途的技术。

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