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Metal-supported SOFC with Ceramic-based Anode

机译:金属支撑的SOFC和陶瓷阳极

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Metal-supported solid oxide fuel cells have shown promise to offer several potential advantages over conventional anode (Ni-YSZ) supported cells, such as increased resistance against mechanical and thermal stresses and a reduction in materials cost. The purpose of this work is to illustrate how the metal-supported cell concept can be combined with ceramic-based anode materials, such as Nb-doped SrTiO_3. The paper shows that a metal-supported cell can have excellent performance by only having electronically conducting phases in the anode backbone structure, into which electrocatalytically active materials are infiltrated after sintering. Initial area specific resistance as low as 0.3 Ωcm~2 at 700 °C has been obtained with power densities > 1 Won~(-2). The initial results on the chemical compatibility, electrochemical performance, and galvanostatic durability of a ceramic based (Nb-doped SrTiO_3), zirconia-free anode, in a planar metal-supported SOFC concept are discussed.
机译:与传统的阳极(Ni-YSZ)支撑的电池相比,金属支撑的固体氧化物燃料电池已显示出有望提供一些潜在的优势,例如,提高了对机械应力和热应力的抵抗力,并降低了材料成本。这项工作的目的是说明如何将金属支撑的电池概念与基于陶瓷的阳极材料(例如掺Nb的SrTiO_3)结合起来。该论文表明,通过在阳极主链结构中仅具有导电相,金属支撑的电池可以具有优异的性能,在烧结后,电催化活性材料会渗入其中。在功率密度> 1 Won〜(-2)的情况下,在700°C时获得的初始面积比电阻低至0.3Ωcm〜2。讨论了在平面金属支撑的SOFC概念中,陶瓷基(掺Nb的SrTiO_3),无氧化锆阳极的化学相容性,电化学性能和恒电流耐久性的初步结果。

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