Studies on the effect of rare earth metal triflates as initiators in the cationic curing of DGEBA/PA systems

机译：稀土金属三氟甲磺酸酯作为引发剂在DGEBA / PA体系阳离子固化中的作用研究

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A new class of cationic initiators, lanthanide triflates, has been studied in the cationic curing of DGEBA/PA mixtures. The reaction mechanism of the cationic curing of DGEBA/PA mixtures has been studied. The kinetics of this process has been evaluated by the Differential Scanning Calorimentry (DSC).The crosslinking degree is predicted from time and temperature of curing via the Gel-curve.

机译：在DGEBA / PA混合物的阳离子固化中，已经研究了一类新型的阳离子引发剂镧系三氟甲磺酸。研究了DGEBA / PA混合物阳离子固化的反应机理。该过程的动力学已通过差示扫描量热法（DSC）进行了评估。交联度是根据通过凝胶曲线固化的时间和温度来预测的。

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《Annual technical conference of the Society of Plastics Engineers;ANTEC 2011》|2011年|p.2323-2327|共5页
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作者
Zhi-Qi Cai; Xin Dong; Xiaofei Wang; Pihui Pi; Xiufang Wen; Jiang Cheng; Zhuoru Yang;
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正文语种
中图分类塑料;有机质材料;
关键词
cationic initiators; cure kinetics; differential scanning calorimentry(dsc); gel-curve;

机译：阳离子引发剂;固化动力学;差示扫描量热法（dsc）;凝胶曲线;

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1. Study on the effect of rare earth metal triflates as initiators in the cationic curing of DGEBA/gamma-valerolactone mixtures and characterization of the thermosets obtained [J] . Arasa M, Ramis X, Salla JM, European Polymer Journal . 2009,第4期

机译：研究稀土金属三氟甲磺酸酯作为引发剂在DGEBA /γ-戊内酯混合物的阳离子固化中的作用以及获得的热固性塑料的特性
2. Cationic copolymerization of DGEBA with two bicyclic bis(gamma-lactone) derivatives using rare earth metal triflates as initiators [J] . Arasa M, Ramis X, Salla JM, Polymer: The International Journal for the Science and Technology of Polymers . 2009,第8期

机译：使用稀土金属三氟甲磺酸酯作为引发剂的DGEBA与两种双环双（γ-内酯）衍生物的阳离子共聚
3. A study of the degradation of ester-modified epoxy resins obtained by cationic copolymerization of DGEBA with γ-lactones initiated by rare earth triflates [J] . Merce Arasa, Xavier Ramis, Josep Maria Salla, Polymer Degradation and Stability . 2007,第12期

机译：稀土三氟甲磺酸酯引发的DGEBA与γ-内酯的阳离子共聚得到的酯改性环氧树脂的降解研究
4. Studies on the effect of rare earth metal triflates as initiators in the cationic curing of DGEBA/PA systems [C] . Zhi-Qi Cai, Xin Dong, Xiaofei Wang, Annual technical conference of the Society of Plastics Engineers . 2011

机译：稀土金属三氟乳酸盐在DGEBA / PA系统阳离子固化中的引发剂的研究
5. A study of the thermodynamics of aqueous rare earth element containing triflate salt systems. [D] . Erickson, Kristy M. 2007

机译：含三氟甲磺酸盐的稀土元素水溶液的热力学研究。
6. DFT Studies on cis-14-Polymerization of Dienes Catalyzed by a Cationic Rare-Earth Metal Complex Bearing an Ancillary PNP Ligand [O] . Xingbao Wang, Xiaohui Kang, Guangli Zhou, 2017

机译：DFT研究带有辅助PNP配体的阳离子稀土金属配合物催化的二烯的顺式14-聚合
7. DFT Studies on cis-1,4-Polymerization of Dienes Catalyzed by a Cationic Rare-Earth Metal Complex Bearing an Ancillary PNP Ligand [O] . Xingbao Wang, Xiaohui Kang, Guangli Zhou, 2017

机译：含有辅助pNp配体的阳离子稀土金属配合物催化二烯的顺式-1,4-聚合的DFT研究

Studies on the effect of rare earth metal triflates as initiators in the cationic curing of DGEBA/PA systems

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