Synthesis and characterization of bis(triaminoguanidinium) 5,5'-dinitrimino-3,3'-azo-1H-1,2,4-triazole - A promising RDX replacement

机译：双（三氨基胍）5,5'-二三氨基-3,3'-偶氮-1H-1,2,4-三唑的合成与表征-一种有希望的RDX替代品

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The synthesis of 5,5'-diamino-3,3'-azo-1H-1,2,4-triazole (3) by reaction of 5-acetylamino-3-amino-1H-1,2,4-triazole (2) with potassium permanganate is described. Compound 3 is used as starting material for the synthesis of 5,5'-dinitrimino-3,3'-azo-1H-1,2,4-triazole (4), which was subsequently reacted with organic bases (ammonia, hydrazine, guanidine, aminoguanidine, triaminoguanidine) to form the corresponding nitrogen-rich triazolate salts (5-9). All substances were fully characterized by IR and Raman as well as multinu-clear NMR spectroscopy, mass spectrometry and differential scanning calorimetry. Selected compounds were additionally characterized by low temperature single crystal X-ray diffraction measurements. Detonation parameters (EXPLO5 code) were calculated based on CBS-4M computed heats of formation. The presented neutral compound as well as the tri-aminoguanidinium salt show detonation performances comparable to RDX. High thermal stabilities and low impact as well as friction sensitivities make the presented nitrogen-rich salts interesting for possible applications as insensitive HEDM.

机译：通过5-乙酰氨基-3-氨基-1H-1,1,2,4-三唑（5）的反应合成5,5'-二氨基-3,3'-偶氮-1H-1,2,4-三唑（3） 2）用高锰酸钾描述。化合物3用作合成5,5'-二三氨基-3,3'-偶氮-1H-1,2,4-三唑（4）的起始原料，然后使其与有机碱（氨，肼，胍，氨基胍，三氨基胍）形成相应的富氮三唑盐（5-9）。所有物质均通过IR和Raman以及多核NMR光谱，质谱和差示扫描量热法进行了全面表征。所选择的化合物还通过低温单晶X射线衍射测量来表征。爆轰参数（EXPLO5代码）是根据CBS-4M计算出的地层热计算得出的。提出的中性化合物以及三氨基胍盐显示出与RDX相当的爆炸性能。高的热稳定性和低的冲击力以及对摩擦的敏感性使所提出的富氮盐对于不敏感的HEDM可能的应用引起了兴趣。

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《Seminar on New Trends in Research of Energetic Materials;NTREM '11》|2012年|p.561-578|共18页
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Alexander Dippold; Thomas M. Klapoetke; Franz A. Martin;
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中图分类爆炸物工业、火柴工业;爆炸物工业、火柴工业;
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triazoles; azo-functionality; nitrogen-rich salts; nitramines;

机译：三唑偶氮官能度富氮盐硝胺;

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1. Synthesis and characterization of bis(triaminoguanidinium) 5,5′-dinitrimino-3,3′-azo-1H-1,2,4-triazolate - A novel insensitive energetic material [J] . Dippold A., Klap?tke T.M., Martin F.A. Zeitschrift fur Anorganische und Allgemeine Chemie . 2011,第9期

机译：双（三氨基胍）5,5'-dinitrimino-3,3'-azo-1H-1,2,4-triazolate的合成与表征-一种新型的不敏感高能材料
2. Synthesis and Promising Properties of a New Family of High-Density Energetic Salts of 5-Nitro-3-trinitromethyl-1H-1,2,4-triazole and 5,5'-Bisdrinitromethyl)-3,3'-azo-1H-1,2,4-triazole [J] . Venugopal Thottempudi, Jeanne M. Shreeve Journal of the American Chemical Society . 2011,第49期

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3. Synthesis and characterization of 3,3′-bis(dinitromethyl)-5,5′- azo-1H-1,2,4-triazole [J] . Dippold A.A., Klap?tke T.M. Zeitschrift fur Anorganische und Allgemeine Chemie . 2011,第11期

机译：3,3'-双（二硝基甲基）-5,5'-偶氮-1H-1,2,4-三唑的合成与表征
4. Synthesis and characterization of bis(triaminoguanidinium) 5,5'-dinitrimino-3,3'-azo-1H-1,2,4-triazole - A promising RDX replacement [C] . Alexander Dippold, Thomas M. Klapoetke, Franz A. Martin Seminar on New Trends in Research of Energetic Materials . 2011

机译：双（Triamoguancinium）的合成与表征5,5'-二硝基氨基-3,3'-AZO-1H-1,2,4-三唑 - 一种有前途的RDX替代品
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机译：（E）-3,3'，4,4'，7,7'，8,8'-八甲基-2H，2'H-1,1'-双（环戊[fg] ac基亚乙烯基）-2,2' ，5,5'，6,6'-己酮二氯甲烷单溶剂化物
7. Cover Feature: Synthesis of gem -Dinitromethylated and Fluorodinitromethylated Derivatives of 5,5′-Dinitro-bis-1,2,4-triazole as Promising High-Energy-Density Materials (Chem. Eur. J. 52/2017) [O] . Shi Huang, Junjun Tian, Xiujuan Qi, 2017

机译：覆盖特征：使用5,5'-二硝基-1,2,4-三唑的珠光硝基甲基化和氟二硝基甲基化衍生物的合成作为高能量密度材料（Chem.Eur。J.52 / 2017）
8. Theoretical Prediction of the Heats of Formation, Densities and Relative Sensitivities, and/or Synthetic Approaches Toward the Synthesis of High Energy Dense Materials (HEDMs): 3,5-Dinitro-1,3,5-Oxadiazinane, Bis-Adjacent RDX, Bis-Adjacent HMX, 4,4',6,6'-Tetranitro-1,1'-Bis(N-oxide)-5,5',6,6'-4H,4'H-5,5'-Bisimidazo Oxadiazole, and the Open-Cage Derivative of CL-20. [R] . Byrd, E. F., Sabatini, J. J. 2015

机译：形成热，密度和相对灵敏度的理论预测，和/或合成高能量密集材料（HEDms）的合成方法：3,5-二硝基-1,3,5-恶二唑烷，双相邻RDX，Bis - 相邻的HmX，4,4'，6,6'-四硝基-1,1'-双（N-氧化物）-5,5'，6,6'-4H，4'H-5,5'-双咪唑恶二唑和CL-20的开笼衍生物。

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Synthesis and characterization of bis(triaminoguanidinium) 5,5'-dinitrimino-3,3'-azo-1H-1,2,4-triazole - A promising RDX replacement

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