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High Performing and Durable Anode-Supported Solid Oxide Fuel Cell by Using Tape Casting, Lamination and Co-firing Method

机译:通过使用带浇铸,层压和共烧法,高性能和耐用的阳极支持的固体氧化物燃料电池

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This work reports development of large-area (12cm×12cm) planar anode-supported SOFC with 100cm~2 active area by a tape casting, lamination and co-sintering method. The cell consists of the nickel-8mol.% yttria-stabilized zirconia as support with 0.7 mm thickness and of the nickel-scandia stabilized zirconia (ScSZ) as an anode functional layer. Processing optimization of binder/plasticizer ratio of tape casting slurry allowed to obtain the green tapes with good mechanical strength and homogenous microstructure. Casting process parameter had also a great influence on the microstructure and mechanical properties of green tapes. The anode-support showed high mechanical strength and sufficient porosity for gas transport. A 6μm thick ScSZ electrolyte and 3μm thick gadolinium-doped ceria (GDC) buffer layer were fabricated using tape casting method and co-firing process. A lanthanum strontium cobalt ferrite-GDC composite cathode was screen-printed on the GDC layer. The single cell showed a peak power density of 509mWcm~(-2) at 750°C.
机译:这项工作通过胶带铸造,层压和共烧制方法报告了大面积(12厘米×12cm)平面阳极支持的SOFC的大面积(12厘米×12cm)平面阳极支持的SOFC。该电池由镍-8mol。%yTTRIA稳定的氧化锆作为载体,厚度为0.7mm,镍钪稳定的氧化锆(SCSZ)作为阳极功能层。加工优化胶带铸造浆料的粘合剂/增塑剂比,以获得具有良好机械强度和均匀微观结构的生坯。铸造工艺参数对绿色胶带的微观结构和机械性能也有很大影响。阳极支持显示出高机械强度和足够的气体运输孔隙率。使用带铸造方法和共烧制制造6μm厚的SCSZ电解质和3μm厚的钆掺杂的二氧化铈(GDC)缓冲层。在GDC层上筛选筛网印刷镧锶铁素体-GDC复合阴极。单细胞在750℃下显示509mWcm〜(-2)的峰值功率密度。

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