Phase relation of FeS_2-VS_2 system and new phase of defect troilite structure

机译：FES_2-VS_2系统的相位关系和缺陷衰脱结构的新阶段

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A large defective troilite (Fe_(0.9)V_(0.1))_(0.82)S is prepared by a sealed silica-tube method at 800°C and characterized by a powder X-ray diffraction method and using a magnetic property measurement system. The crystal structures of a defective troilite and non defective troilite are analyzed by Rietveld method. The large defect enhances the Fe-Fe pairing and suppresses the waving of Fe-chain along c-direction. The antiferromagnetic property is observed on both troilites. The spin-flip transition temperature of the large defective troilite is 9K.

机译：通过在800℃下通过密封的二氧化硅 - 管方法制备大的缺陷岩土石（Fe_（0.9）V_（0.1））_（0.82）S，并通过粉末X射线衍射方法表征并使用磁性测量系统。通过RIETVELD方法分析缺陷杂质石和无缺陷杂质石的晶体结构。大缺陷增强了Fe-Fe配对，抑制了沿C方向的Fe链的挥手。在两种毛虫上观察到反铁磁性。大有缺陷性胸腺的旋转转变温度为9K。

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《International Conference on Solid Compounds of Transition Elements》|2011年||共5页
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Yoshihisa Miyata; Koya Hayashi; Genta Sakane; Takaaki Arimoto; Yasuhiro Katayama; Mamoru Shimakawa;
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中图分类工程材料一般性问题;
关键词
Troilite; FeS; Defect; Phase relation; Crystal structure; Magnetic property;

机译：毒脂;FES;缺陷;相位关系;晶体结构;磁性;

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1. Phase relation of FeS_2-VS_2 system and new phase of defect troilite structure [J] . Miyata Y., Hayashi K., Sakane G., Diffusion and Defect Data. Solid State Data, Part B. Solid State Phenomena . 2011,第Null期

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4. Phase relation of FeS_2-VS_2 system and new phase of defect troilite structure [C] . Yoshihisa Miyata, Koya Hayashi, Genta Sakane, International Conference on Solid Compounds of Transition Elements . 2011

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Phase relation of FeS_2-VS_2 system and new phase of defect troilite structure

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