首页> 外文会议>International Conference on Advanced Batteries, Accumulators and Fuel Cells >Chemometric approach to study the influence of synthesis parameters on the structural and electrical responses of metal polycyanometalates (MPCMs) for optimizing their use as cathodes in metal(M)-ion batteries (M = Li+, K+, Na+).
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Chemometric approach to study the influence of synthesis parameters on the structural and electrical responses of metal polycyanometalates (MPCMs) for optimizing their use as cathodes in metal(M)-ion batteries (M = Li+, K+, Na+).

机译:化学计量方法研究合成参数对金属多环酸盐(MPCMS)结构和电响应的影响优化金属(M = Li +,K +,Na +)优化它们的用作阴极用作阴极。

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In the last time, the growing demand for energy has led to the search for new technologies for the storage of energy. Electrochemical batteries have been seen as a good option, where the most known are the type Metal-ion batteries (MIBs), based on the electrochemical intercalation of the ions and being recognized as a promising alternative (1). The choice of cathode materials significantly affects the performance and cost of a M-ion battery. Therefore, is necessary to use inexpensive cathode materials could reduce the overall cost of MIBs and expand their application for energy storage (2). From this point of view, transition metal polycyanometometalates (MPCMs) could be considered as promising candidates. They possess an open framework where an intercalation process of ions presents in the electrolyte can occur (Figure 1). In this last process, a redox change of the central metal atom should happen simultaneously. Therefore, such compounds can be used as ionic host structures in the design of cathodes for M-ion batteries.
机译:在最后一次,对能源的日益增长的需求导致了寻找能源存储的新技术。电化学电池已被视为良好的选择,其中最着名的是金属离子电池(MIBS),基于离子的电化学插入并被认识为有前途的替代方案(1)。阴极材料的选择显着影响M离子电池的性能和成本。因此,必须使用廉价的阴极材料可以降低MIB的总成本,并扩大其对能量存储(2)的应用。从这个角度来看,过渡金属多环素液(MPCMS)可以被认为是有前途的候选者。它们具有开放的框架,可以发生电解质中的离子的嵌入过程(图1)。在最后一个过程中,中央金属原子的氧化还原变化应该同时发生。因此,这些化合物可以用作用于M离子电池的阴极的离子宿主结构。

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