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Short-Time Events,Coherence, and Structural Dynamics in Photochemistry of Aqueous Halogenated Transition Metal Dianions

机译:卤化过渡金属圆核水溶液中的短时事件,连贯性和结构动力学

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摘要

Ultrafast pump-probe spectroscopy, time-resolved x-ray absorption, and computational photochemistry elucidate the photochemical pathway of hexabromoplatinate dianions that propagates through distortions of nascent penta-bromoplatinate anions caused by Jahn-Teller conical intersections and terminates at aquated product complexes.
机译:超快泵探测光谱,时间分辨X射线吸收和计算光化学阐明了六溴化术的光化学途径,通过JAHN-Teller Conical Intertects引起的新生Penta-溴化术阴性的扭曲和终止于水生产品复合物的扭曲。

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