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Synthesis of porous CaO microsphere and its application in catalyzing transesterification reaction for biodiesel

机译:多孔CaO微球的合成及其在生物柴油酯交换反应中的应用。

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It is hoped to develop a simple and low cost route for preparing the CaO with a novel morphology which can present high catalytic activity in catalyzing transesterification reaction for biodiesel. The porous CaO microsphere was synthesized by calcining spherical CaCO3 precursor which was prepared easily by mixing CaCl2 with Na2CO3. The as-prepared Cao microsphere was characterized by scanning electronic microscopy(SEM), powder X-ray diffractometry(XRD) and N2 adsorption experiment. The results reveal that the synthesized CaO is regular microsphere with many pores in its exterior and interior. The Cao microsphere is applied in catalyzing the transesterification reaction of soybean oil for biodiesel and presents excellent catalytic ability with a transesterification yield of 98.72%. This catalyst could have potential applications in other fields in view of its well-defined morphology, simply synthetic route and low cost.
机译:希望开发一种简单且低成本的制备具有新颖形态的CaO的方法,该CaO在催化生物柴油的酯交换反应中具有较高的催化活性。通过煅烧球形CaCO3前体来合成多孔CaO微球,该球形CaCO3前体易于通过将CaCl2与Na2CO3混合而制备。通过扫描电子显微镜(SEM),粉末X射线衍射(XRD)和N2吸附实验对制备的曹微球进行了表征。结果表明,合成的CaO是规则的微球,其内部和外部都有许多孔。 Cao微球用于催化大豆油对生物柴油的酯交换反应,具有优异的催化能力,酯交换率为98.72%。鉴于其明确的形态,简单的合成路线和低成本,该催化剂可能在其他领域具有潜在的应用。

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