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Efficient Red Light-Emitting Diodes Based on Novel Europium Complexes in Poly(9,9-Dioctylfluorene) Host

机译:新型(9,9-二辛基芴)主体中基于新型Euro配合物的高效红光发光二极管

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The derivatives of tri(4,4,4-trifluoro-l-phenyl-1,3- butanedione) (1,10-phenanthro1ine) europium(Ⅲ) (Eu(TPD)3Phen), i.e. Eu(Ph-TPD)3Phen and Eu(BiPh-TPD)3Phen, were synthesized. Efficient red polymer light-emitting diodes (PLEDs) based on the europium complexes are fabricated with poly(9,9-dioctylfluorene) (PFO) in the presence of 30 wt.% electron-transporting compound 2-(4biphenylyl)-5-(ptertbutylpheny1)-1,3,4oxadiazole (PBD) as the host. A significant improvement in the electroluminescent (EL) performances was observed by increasing the conjugated length of the europium complexes, and for the complex Eu(TPD)3Phen, Eu(Ph-TPD)3Phen and Eu(BiPh-TPD)3Phen, the maximum luminance efficiency were respectively 0.12 cd/A, 0.45 cd/A and 1.27 cd/A, and the maximum brightness were 54 cd/m2, 91 cd/m2 and 231 cd/m2, respectively.
机译:三(4,4,4-三氟-1-苯基-1,3-丁二酮)(1,10-菲咯啉)euro(III)(Eu(TPD)3Phen)的衍生物,即Eu(Ph-TPD)3Phen合成了Eu(BiPh-TPD)3Phen。在30 wt。%电子传输化合物2-(4biphenylyl)-5-( ptertbutylpheny1)-1,3,4oxadiazole(PBD)作为宿主。通过增加the配合物的共轭长度,可以观察到电致发光(EL)性能的显着改善,对于配合物Eu(TPD)3Phen,Eu(Ph-TPD)3Phen和Eu(BiPh-TPD)3Phen,最大值亮度效率分别为0.12 cd / A,0.45 cd / A和1.27 cd / A,最大亮度分别为54 cd / m2、91 cd / m2和231 cd / m2。

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