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Characterization of the hydrolysis of corn stover catalyzed by inorganic Fe salt for biogas production

机译:沼气生产无机二盐催化玉米秸秆水解的特征

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Two inorganic salts, FeCl3 and Fe(NO3)3, were chosen as catalysts to determine their effects on the hydrolysis of corn stover, and the results indicated that Fe(NO3)3 was one of the most efficient catalyst for the hydrolysis of hemicelluloses. The kinetics of the hydrolysis reaction of corn stover catalyzed by Fe(NO3)3 were investigated at different temperatures. The results showed that two-fraction model fitted very well the hydrolysis reaction of hemicelluloses catalyzed by Fe(NO3)3, and the kinetic parameters for this model were obtained by nonlinear regression using the Newton s method. The activation energies for the hydrolysis of hemicelluloses in corn stover was 91.79 kJ/mol calculated by the classic Arrhenius equation. Optimum pretreatment conditions were 0.05 mol/L Fe(NO3)3 at 150 °C for 16.5 min, which obtained the maximum xylose yields 91.3% of initial xylan.
机译:选择两种无机盐,FECL3和Fe(NO3)3作为催化剂,以确定它们对玉米秸秆水解的影响,结果表明Fe(NO3)3是半纤维素水解的最有效催化剂之一。在不同的温度下研究了用Fe(NO 3)3催化的玉米秸秆水解反应的动力学。结果表明,两馏分模型非常稳定,通过Fe(NO 3)3催化的半纤维素的水解反应,并通过使用牛顿方法的非线性回归获得该模型的动力学参数。玉米秸秆中半纤维素水解的活化能量为91.79kJ / mol,通过经典的Arhenius方程计算。最佳预处理条件为150℃的最佳预处理条件为0.05mol / L Fe(NO 3)3,持续16.5分钟,其获得最大木糖产生91.3%的初始木聚糖。

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