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Optical stimulated thermoluminescence in Silicon Rich Oxide nanostructured films

机译:富氧化硅纳米结构薄膜中的光激发热致发光

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In this work, it is study thermoluminescent phenomena (TL) optically stimulated with UV radiation in Silicon Rich Oxide (SRO) nanostructured thin films. The experimental samples used were thin films of this composite deposited by Low Pressure Chemical Vapor Deposition (LPCVD) over a n-type silicon substrate, this samples were fabricated using different flow ratios of precursory gases silane and nitrous oxide R_0=SiH_4/H_2O during the deposition and were given posterior thermal treatment which gave place to the formation of different sized nanoparticles, that are attributed to the luminescent activation mechanism in this material. The silicon excess was controlled by the ratio of the gases used in the deposition process and in this way SRO films with 12, 8 and 6% silicon excess were obtained. The glow-curves experimentally obtained were submitted to analysis using different models in order to obtain important thermoluminescent parameters. The luminescence spectra of SRO show two wavelength regions of emission; one in the blue part and one in the red part of the emission spectrum. The emission in the blue part is related to defects in the SiO lattice. About the origin of the red luminescence there is still a controversy. One model assumes that the red luminescence stems from Si nano particles and another model assumes that defects at the interface of SiO bulk with the Si nano particle are responsible for the red luminescence. Finally is intended to provide favorable conditions for the development of a UV dosimeter with this material.
机译:在这项工作中,它是研究热致发光现象(TL)用富含硅氧化物(SrO)纳米结构薄膜的UV辐射光学刺激。所用的实验样品是在N型硅衬底上通过低压化学气相沉积(LPCVD)沉积该复合材料的薄膜,使用预体气体的不同流动比和氧化亚氮r_0 = siH_4 / h_2o制造该样品沉积并给予后热处理,其归因于形成不同尺寸的纳米颗粒,其归因于该材料中的发光活化机制。通过在沉积过程中使用的气体的比率来控制硅过量,并以这种方式获得12,8和6%硅过量的SrO膜。实验所得的发光曲线被提交以使用不同型号的分析,以获得重要的热辐发光参数。 SRO的发光光谱显示出两个波长区域的发射区域;一个在蓝色部分,一个在发射光谱的红色部分中。蓝部件中的发射与SiO格中的缺陷有关。关于红色发光的起源仍然存在争议。一种模型假设红色发光源于Si纳米颗粒,另一种模型假定与Si纳米颗粒的SiO块膜界面处的缺陷负责红色发光。最后旨在为具有这种材料的紫外剂量表的开发提供有利的条件。

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