MORPHOLOGICAL CHARACTERIZATION OF MECHANICALLY ALLOYED PET/VECTRA BLENDS BY X-RAY MICROSCOPY

机译：通过X射线显微镜机械合金化PET / Vectra共混物的形态学特征

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High-energy mechanical milling constitutes a novel means by which to produce intimate mixtures of immiscible polymers. In the present work, this technique has been employed to blend poly(ethylene terephthalate) (PET) and a thermotropic copolyester (Vectra). Morphological characterization by conventional transmission electron microscopy (TEM) is confounded due to the absence of a preferential stain to enhance phase contrast. Based on Near Edge X-ray Absorption Fine Structure spectroscopy, x-ray microscopy is sensitive to the chemistry and orientation of functional groups and can be used to discriminate between PET and Vectra. X-ray micrographs reveal that PET-rich blends exhibit Vectra-rich domains ranging from 0.10 to 20 μm in diameter. X-ray microscopy is also utilized here to determine the molecular orientation within the Vectra-rich domains.

机译：高能量机械研磨构成一种新颖的方法，由此产生一种不混溶的聚合物的紧密混合物。在本作工作中，该技术已经用于混合聚（乙二醇酯）（PET）和热致丙二醇共聚酯（Vectra）。由于不存在优先染色以增强相位对比度，通过常规透射电子显微镜（TEM）的形态学表征被混淆。基于近边缘X射线吸收细结构光谱，X射线显微镜对功能组的化学和取向敏感，可用于区分PET和Vectra。 X射线显微照片揭示了富宠物的共混物表现出直径0.10至20μm的Vectra的富座。此处还用于X射线显微镜检查以确定富焦域内的分子取向。

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《Society of Plastics Engnieers annual technical conference》|1998年||共5页
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A. P. Smith; C. Bai; H. Ade; R. J. Spontak; C. M. Balik; C. C. Koch; C. K. Saw;
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1. X-ray microscopy of novel thermoplastic/liquid crystalline polymer blends by mechanical alloying [J] . Smith AP., Ade H., Spontak RJ., Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation . 1998,第11期

机译：机械合金化的新型热塑性/液晶聚合物共混物的X射线显微镜
2. Mg2Cu Alloy Preparation by Mechanical Alloying Process and Its Characterization Using X-ray Diffraction and Scanning Electron Microscopy [J] . José Luis Iturbe-Garcia, Beatriz Eugenia López-Mu?oz, Luis Zamora Rangel American Chemical Science Journal . 2015,第4期

机译：机械合金化制备Mg2Cu合金及其X射线衍射和扫描电子显微镜表征
3. Exploring Mechanical, Thermal, Morphological and Rheological Properties of Polypropylene-Liquid Crystalline Polymer (Vectra-A950) Blends [J] . P.K. MANDAL, S.K. SIDDHANTA, D. CHAKRABORTY Journal of Polymer Materials . 2010,第1期

机译：探索聚丙烯-液晶聚合物（Vectra-A950）共混物的机械，热，形态和流变性能
4. MORPHOLOGICAL CHARACTERIZATION OF MECHANICALLY ALLOYED PET/VECTRA BLENDS BY X-RAY MICROSCOPY [C] . A. P. Smith, C. Bai, H. Ade, Conference Proceedings at ANTEC '98 . 1998

机译：机械合金化PET / VEC混合料的X射线显微镜形貌表征
5. The solid state blending of polymers via cryogenic mechanical alloying: Effects on blend morphology and thermal transitions [D] . Schexnaydre, Ryan J. 2008

机译：通过低温机械合金化进行聚合物的固态共混：对共混物形态和热转变的影响
6. The Effect of Injection Molding Temperature on the Morphology and Mechanical Properties of PP/PET Blends and Microfibrillar Composites [O] . Maja Kuzmanović, Laurens Delva, Ludwig Cardon, 2016

机译：注塑温度对PP / PET共混物和微原纤复合材料形态和力学性能的影响
7. Synthesis, characterization and mechanical properties of (Al, Cu)3Ti powder blend by mechanical alloying [O] . Behera S 2014

机译：机械合金化制备（Al，Cu）3Ti粉末混合物的合成，表征及力学性能

MORPHOLOGICAL CHARACTERIZATION OF MECHANICALLY ALLOYED PET/VECTRA BLENDS BY X-RAY MICROSCOPY

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