Removal of CO from Methanol Reforming Gas by Low Temperature Shift Reaction

机译：低温换档反应除去甲醇重整气体的CO

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Copper catalysts supported on mixed oxides were investigated for CO removal in the methanol steam reformed gas. Although Cu/Al_2O_3-ZnO demonstrated excellent activity for water gas shift reaction (WGSR; CO + H_2O ->CO_2 + H_2), further removal of CO in the reformed gas applied as a fuel for polymer electrolyte fuel cells is required. It is difficult to remove trace CO in the reformed gas through WGSR, however, O_2 addition to the reformed gas is effective to enhance the CO removal through CO oxidation. Cu/Al_2O_3-ZnO also demonstrated excellent activity for catalytic removal of CO by WGSR and selective CO oxidation (CO + 1/2O_2 ->CO_2). This indicates that the design of an active shift/oxidation catalyst operative at 100-150 °C is a possible method for selective removal of CO in the methanol reforming gas.

机译：研究了在甲醇蒸汽重整气体中的铜催化剂中负载的铜催化剂。虽然Cu / Al_2O_3-ZnO证明了水煤气变换反应的优异活性（WGSR; CO + H_2O - > CO_2 + H_2），但需要进一步除去作为聚合物电解质燃料电池燃料的重整气体中的CO。难以通过WGSR除去重整气体中的痕量CO，但是，改性气体的O_2加入是有效增强通过共氧化的共同除去。 Cu / Al_2O_3-ZnO还通过WGSR和选择性共氧化（CO + 1 / 2O_2 - > CO_2）来证明了催化除去CO的优异活性。这表明在100-150℃下操作的活性换档/氧化催化剂的设计是选择性除去甲醇重整气体中的CO的可能方法。

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《Tokyo conference on advanced catalytic science and technology》|1999年||共4页
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Koichi Eguchi; Sei-ichi Yano; Toshimasa Utaka; Koshi Sekizawa; Hiromichi Arai;
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中图分类催化反应过程;
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1. CO removal from methanol reformed gas by oxygen- assisted CO shift reaction [J] . T. Utaka, Y. Tanaka 触媒 . 2000,第2期

机译：通过氧气辅助的CO变换反应从甲醇重整气中去除CO
2. CO removal from methanol reformed gas by oxygen- assisted CO shift reaction [J] . T. Utaka, Y. Tanaka 触媒 . 2000,第2期

机译：通过氧辅助CO换档反应从甲醇重整气体中除去
3. PdZnAl catalysts for the reactions of water-gas-shift,methanol steam reforming,and reverse-water-gas-shift [J] . R.A.Dagle, A.Platon, D.R.Palo Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2008,第1a2期

机译：PdZnAl催化剂用于水煤气变换，甲醇蒸汽重整和反向水煤气变换的反应
4. Removal of CO from Methanol Reforming Gas by Low Temperature Shift Reaction [C] . Koichi Eguchi, Sei-ichi Yano, Toshimasa Utaka, Tokyo conference on advanced catalytic science and technology . 1999

机译：低温换档反应除去甲醇重整气体的CO
5. Catalytic steam reforming of methanol using a commercial copper oxide/zinc oxide/aluminum oxide low temperature shift catalyst (copper oxide, zinc oxide, aluminum oxide). [D] . Peppley, Brant Anthony Davis. 1993

机译：使用市售的氧化铜/氧化锌/氧化铝低温变换催化剂（氧化铜，氧化锌，氧化铝）催化甲醇的水蒸气重整。
6. Impact of Incorporation of Active Nanoporous Componentsor Their Precursors in a CuAlO/CuAl Ceramometal Skeleton on the Propertiesin the Low-Temperature Water-Gas Shift Reaction [O] . Serguei F. Tikhov, Tatyana P. Minyukova, Konstantin R. Valeev, 2020

机译：掺入活性纳米多孔组分的影响或它们在性质上的Cualo / Wual陶瓷骨架中的前体在低温水气移反应中
7. PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol Steam Reforming, and Reverse-Water-Gas-Shift [O] . Dagle, R. A, Platon, A., Palo, D. R., 2008

机译：PdZnAl催化剂用于水煤气变换，甲醇蒸汽重整和水煤气变换反向反应
8. Water Gas Shift Reaction with a Single Stage Low Temperature Membrane Reactor. [R] . Ciora, R. J., Liu, P. K. 2013

机译：单级低温膜反应器的水煤气变换反应。

Removal of CO from Methanol Reforming Gas by Low Temperature Shift Reaction

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