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Modified Polypropylenes by Copolymerization with Nonconjugated Dienes and Additional Chemical Reactions

机译：通过与非共轭二烯的共聚合和另外的化学反应进行改性聚丙烯

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Modified polypropylenes were synthesized by Copolymerization of propene with several nonconjugated dienes using a constrained geometry catalyst in combination with methylaluminoxane. The incorporation of the dienes yields in polymer structures containing both cyclic units and linear branches, respectively. By variation of the polymerization conditions the cyclization tendency can be reduced. The resulting propene/diene copolymers are equipped with higher amounts of pendant double bonds which can be used for following chemical reactions. As an example, the epoxidation of the free double bonds was carried out using several epoxidation reagents. In a further modification step, the ring opening of the epoxy groups is presented demonstrating the simplicity of the chemical modification possibilities of such polypropylene materials.

机译：通过使用约束的几何催化剂与甲基铝氧烷组合的具有几个非共轭二烯的丙烯共聚合通过与几个非共轭二烯共聚合成改性聚丙烯。将二烯的掺入分别在含有循环单元和线性分支的聚合物结构中产生。通过聚合条件的变化，可以降低环化趋势。所得丙烯/二烯共聚物配备有较多的垂料双键，其可用于以下化学反应。作为一个例子，使用几种环氧化试剂进行游离双键的环氧化。在进一步的修改步骤中，呈现环氧基的环开口，证明了这种聚丙烯材料的化学改性可能性的简单性。

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《Conference on Osterreichische polymertage》|2002年||共12页
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Manfred Arnold; Steffen Bornemann; Thomas Schimmel; Thomas Heinze; Macromolecular Symposia 181;
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中图分类碳链聚合物;
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1. Copolymerization of Isoprene and Nonconjugated α,ω-Dienes by Half-Sandwich Scandium Catalysts with and without a Coordinative Side Arm [J] . Fang Guo, Masayoshi Nishiura, Yang Li, Chemistry, an Asian journal . 2013,第10期

机译：带有和不带有配位侧臂的半夹心Scan催化剂对异戊二烯和非共轭α，ω-二烯的共聚合
2. Living regioselective copolymerization of ethylene with nonconjugated bicyclic dienes using (salicylaldiminato)(β-enaminoketonato) titanium catalysts [J] . Long Y.-Y., Wang Y.-X., Liu J.-Y., Journal of Polymer Science, Part A. Polymer Chemistry . 2011,第21期

机译：使用（水杨基铝二氨基）（β-烯胺酮）钛催化剂的乙烯与非共轭双环二烯的活性区域选择性共聚
3. Living Coordinative Chain-Transfer Polymerization and Copolymerization of Ethene, alpha-Olefins, and alpha,omega-Nonconjugated Dienes using Dialkylzinc as "Surrogate" Chain-Growth Sites [J] . Zhang W, Wei J, Sita LR Macromolecules . 2008,第21期

机译：以二烷基锌为“替代”链增长点的乙烯，α-烯烃和α，ω-非共轭二烯的活性配位链转移聚合和共聚
4. Modified Polypropylenes by Copolymerization with Nonconjugated Dienes and Additional Chemical Reactions [C] . Manfred Arnold, Steffen Bornemann, Thomas Schimmel, Conference on Osterreichische polymertage . 2002

机译：通过与非共轭二烯的共聚合和另外的化学反应进行改性聚丙烯
5. Palladium-catalyzed coupling of aryl iodides, nonconjugated dienes and nucleophiles. [D] . Wang, Yao. 1995

机译：钯催化的芳基碘化物，非共轭二烯和亲核试剂的偶联。
6. Synthesis of Ultrahigh Molecular Weight Polymers Containing Reactive Functionality with Low PDIs by Polymerizations of Long-Chain α-Olefins in the Presence of Their Nonconjugated Dienes by Cp*TiMe2(O-26-iPr2C6H3)–Borate Catalyst [O] . Kotohiro Nomura, Sarntamon Pengoubol, Wannida Apisuk 2020

机译：Cp * TiMe2（O-26-iPr2C6H3）-硼酸盐催化剂在长链α-烯烃非共轭二烯存在下的聚合反应合成具有低PDI活性的超高分子量聚合物
7. Photochemical nucleophile–olefin combination, aromatic substitution (photo-NOCAS) reaction. Part 6: methanol, nonconjugated dienes, and 1,4-dicyanobenzene [O] . Donald R. Arnold, Kimberly A. McManus, Xinyao Du 1994

机译：光化学核官烯烃组合，芳香替代（光 - NOCAS）反应。第6部分：甲醇，非共轭二烯和1,4-二氯苯苯
8. Thermal Reactions of Ru(CO)3(C2H4)2 with Acyclic, Non-Conjugated Dienes and Photochemistry of Ru(CO)4(eta(2)-diene) Complexes [R] . Wuu, Y. M., Wrighton, M. S. 1988

机译：Ru（CO）3（C2H4）2与非环状非共轭二烯的热反应和Ru（CO）4（η（2） - 二烯）配合物的光化学

Modified Polypropylenes by Copolymerization with Nonconjugated Dienes and Additional Chemical Reactions

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