首页> 外文会议>Tokyo Conference on Advanced Catalytic Science and Technology >Effect of Cyclopentadienyl Fragment in Polymerization of EthySene, Propylene, and Styrene by Nonbricfged Half-Metalloce Type Titanium and Zirconium Complexes of the Type, Cp'MCfe N(2,6-Me_2 C_ H_3)(SiMe_3), -MAO Catalyst Systems

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Effect of Cyclopentadienyl Fragment in Polymerization of EthySene, Propylene, and Styrene by Nonbricfged Half-Metalloce Type Titanium and Zirconium Complexes of the Type, Cp'MCfe N(2,6-Me_2 C_ H_3)(SiMe_3), -MAO Catalyst Systems

机译：乙烯化苯甲酰基团在乙烯，丙烯和苯乙烯聚合中的非脆性半金属型钛和锆络合物的聚合，CP'MCFE n（2,6-ME_2C_3）（SIME_3），-MAO催化剂体系

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Various (anilide)(cyclopentadienyl)titanium(IV) complexes of type, Cp'MCl_2[N(2,6-Me_2C_6H_3)-(SiMe_3)] [M = Ti and Cp' = C_5Me_5 (Cp~*, 1), l,3-Me_2C_5H_3 (2), C_5H_5 (Cp, 3); M = Zr and Cp' = Cp~* (4)], have been cliosen for polymerization of ethylene, propylene, and styrene in the presence of methylaluminoxane (MAO). 1 was found to exhibit the highest catalytic activity for ethylene polymerization whereas 3 showed the highest catalytic activity for syndiospecific styrene polymerization. These results clearly show that efficient catalyst for the desired polymerization can be modified only by changing the substituent on cyclopentadienyl group.

机译：类型的各种（苯氧化锡）（环戊二烯基）钛（IV）复合物，CP'MCL_2 [n（2,6-ME_2C_6H_3） - （SIME_3）] [M = TI和CP'= C_5ME_5（CP〜*，1），L ，3-me_2c_5h_3（2），c_5h_5（cp，3）; M = Zr和CP'= CP〜*（4）]，是在甲基铝氧烷（MAO）存在下乙烯，丙烯和苯乙烯的聚合的Closen。发现乙烯聚合的催化活性最高，而3显示了Syndiophicific苯乙烯聚合的最高催化活性。这些结果清楚地表明，仅通过改变环戊二烯基的取代基来改变所需聚合的有效催化剂。

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《Tokyo Conference on Advanced Catalytic Science and Technology》|2003年||共4页
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Kotohiro Nomura; Kensaku Fujii;
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1. Effect of cyclopentadienyl and amide fragment in olefin polymerization by nonbridged (amide)(cyclopentadienyl)titanium(IV) complexes of the type Cp ' TiCl2[N(R-1)R-2]-methylaluminoxane (MAO) catalyst systems [J] . Nomura K., Fujii K. Macromolecules . 2003,第8期

机译：Cp'TiCl2 [N（R-1）R-2]-甲基铝氧烷（MAO）催化剂类型的非桥接（酰胺）（环戊二烯基）钛（IV）配合物在烯烃聚合中对环戊二烯基和酰胺片段的影响
2. Effect of ketimide ligand for ethylene polymerization and ethyleneorbornene copolymerization catalyzed by (cyclopentadienyl)(ketimide)titanium complexes-MAO catalyst systems: Structural analysis for Cp*TiCl2(N=CPh2) [J] . Nomura K, Yamada J, Wang W, Journal of Organometallic Chemistry . 2007,第21期

机译：酮亚胺配体对（环戊二烯基）（酮亚胺）钛配合物-MAO催化剂体系催化乙烯聚合和乙烯/降冰片烯共聚的影响：Cp * TiCl2（N = CPh2）的结构分析
3. Factors affecting product distributions in ethylene/styrene copolymerization by (aryloxo)(cyclopentadienyl)titanium complexes-MAO catalyst systems [J] . Nomura K, Zhang H, Byun DJ Journal of Polymer Science, Part A. Polymer Chemistry . 2008,第12期

机译：（芳基氧代）（环戊二烯基）钛配合物-MAO催化剂体系在乙烯/苯乙烯共聚中影响产物分布的因素
4. Effect of Cyclopentadienyl Fragment in Polymerization of EthySene, Propylene, and Styrene by Nonbricfged Half-Metalloce Type Titanium and Zirconium Complexes of the Type, Cp'MCfe N(2,6-Me_2 C_ H_3)(SiMe_3), -MAO Catalyst Systems [C] . Kotohiro Nomura, Kensaku Fujii Tokyo Conference on Advanced Catalytic Science and Technology . 2003

机译：乙烯化苯甲酰基团在乙烯，丙烯和苯乙烯聚合中的非脆性半金属型钛和锆络合物的聚合，CP'MCFE n（2,6-ME_2C_3）（SIME_3），-MAO催化剂体系
5. Chelating diamide complexes of titanium, zirconium and scandium: New polymerization catalysts based on non-Cp ligand environments. [D] . Scollard, John David. 1998

机译：钛，锆和scan的螯合二酰胺配合物：基于非Cp配体环境的新型聚合催化剂。
6. Highly Active and Isospecific Styrene Polymerization Catalyzed by Zirconium Complexes Bearing Aryl-substituted OSSO-Type Bis(phenolate) Ligands [O] . Norio Nakata, Tomoyuki Toda, Yusuke Saito, 2016

机译：含芳基取代的OSSO型双酚盐配体的锆配合物催化高活性和异规苯乙烯聚合
7. Living Copolymerization of Ethylene with Styrene Catalyzed by (Cyclopentadienyl)(ketimide)titanium (IV) Complex-MAO Catalyst System [O] . -1

机译：（环戊二烯基）（乙腈）钛（IV）复合物催化剂体系催化乙烯与苯乙烯共聚

Effect of Cyclopentadienyl Fragment in Polymerization of EthySene, Propylene, and Styrene by Nonbricfged Half-Metalloce Type Titanium and Zirconium Complexes of the Type, Cp'MCfe N(2,6-Me_2 C_ H_3)(SiMe_3), -MAO Catalyst Systems

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