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Raman spectra and pressure-induced lattice instabilities in RbMnCl3 crystal

机译:RBMNCL3晶体中拉曼光谱和压力诱导的晶格稳定性

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Raman scattering spectra of the RbMnCl3 crystal have been studied under ambient conditions and under high hydrostatic pressure. The results produced have been interpreted with the ab initio model. The experimental data agree well with the estimated values in the low frequency range and show a slightly worse agreement at higher frequencies. A phase transition from the hexagonal phase to the perovskite phase predicted earlier within the same model was observed under high pressure (above 0.7 GPa) and new transitions to lower symmetry phases were found at higher pressures (1.1 GPa and 5 GPa).
机译:已经在环境条件下和高静液压压力下研究了RBMNCL3晶体的拉曼散射光谱。产生的结果已被AB Initio模型解释。实验数据与低频范围内的估计值吻合良好,并且在较高频率下显示略差更差。在高压(高于0.7GPa)的高压(高于0.7GPa)下观察到从六方相到预测的钙钛矿相的相转变,并在较高的压力(1.1GPa和5GPa)下发现对对称相的新转变。

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