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Characteristics of Volatile Organic Compounds in the Atmosphere at the Surrounding Area of an Oil-Contaminated Remediation Site

机译:油污修复部位周边地区大气中挥发性有机化合物的特征

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This study aims to investigate the characteristics of atmospheric volatile organic compounds (VOCs) emitted from an oil-contaminated remediation site. A sampling network including five sampling sites located at the surrounding area of the oil-contaminated remediation site and nearby community was established for sampling VOCs near ground level. In this study, VOCs were collected by carbontrap 300 packed multi-bed sampling tubes from February 2002 to April 2003. The tubes were then desorbed by a thermal desorption unit (TDU) and then analyzed by a gas chromatography with a flame ionization detector (GC/FID). In addition, methane and non-methane hydrocarbons (NMHC) were automatically monitored in-situ and correlated with the concentration of VOCs. Results from field measurements showed that the concentration of NMHC at the upwind of oil-contaminated remediation site was generally lower than the downwind site at nearby community. Major VOCs observed in the atmosphere were n-octane, toluene, and m,p-xylene. The mass ratios of toluene to benzene (T/B) were similar to the tail pipe exhaust gas's T/B of 2.0-2.3. Similar trend was observed for the mass ratio of benzene, toluene, ethylbenzene, and m,p-xylene (BTEX). The results suggested that the atmospheric VOCs at the surrounding area of the oil-contaminated remediation site was mainly emitted from automobiles on the highway rather than from soil gas emitted from oil-contaminated remediation site. Health risk assessment indicated that the cancer risk criteria ranged from 1.1x10~(-9) to 7.8x10~(-8), while the non-cancer hazard indexes ranged from 8.4x10~(-5) to 3.7x10~(-3). Both cancer and non-cancer hazard risks did not violate the regulation of 1.0x10~(-6) and unity, respectively.
机译:本研究旨在探讨从污染的修复部位发出的大气挥发性有机化合物(VOC)的特征。一个采样网络,包括位于油污污染的修复站点周围地区和附近社区的五个采样网站,为在地面上的采样VOC。在这项研究中,从2002年2月到2003年4月,通过Carbontrap 300包装的多床采样管收集VOC。然后通过热解吸单元(TDU)解吸管,然后通过气相色谱法分析火焰电离检测器(GC / FID)。此外,甲烷和非甲烷烃(NMHC)原位监测并与VOC的浓度相关。现场测量结果表明,油污修复部位逆风的NMHC浓度通常低于附近社区的下行部位。在大气中观察到的主要VOC是N-辛烷,甲苯和M,对二甲苯。甲苯与苯(T / B)的质量比类似于2.0-2.3的尾管废气的T / B。苯,甲苯,乙苯和M,对二甲苯(BTEX)的质量比观察到类似的趋势。结果表明,油污修复部位周围地区的大气VOC主要主要从高速公路上的汽车发出,而不是从污染的修复部位发出的土壤气体。健康风险评估表明,癌症风险标准从1.1x10〜(-9)到7.8x10〜(-8),而非癌症危险指标从8.4x10〜(-5)到3.7x10〜(-3 )。癌症和非癌症危害风险都没有分别违反1.0×10〜(-6)和统一的调节。

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