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GC/MS ANALYSES OF THE VOLATILE COMPOUNDS OF Tuber Melanosporum FROM TRICASTIN AND ALPES DE HAUTE PROVENCE (FRANCE)

机译:来自三仙蛋白和Alpes de Haute Provence(法国)的块茎黑素孢子族挥发性化合物的GC / MS分析

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Black truffle (Tuber melanosporum) aromas from two different areas of Southern France: i) Tricastin (Richerenches) and ii) Alpes de Haute Provence (Simiane) have been studied by two different extraction methods: a) extraction using pentane and ethyl ether as the solvents, and b) solid phase micro extraction (SPME). A total of 131 compounds have been identified by GC/MS and retention indices. Chemical composition was found to be different according to areas and extraction methods. An interesting fraction of black truffles from Tricastin, obtained by SPME method, consisted of heterocyclic compounds most likely arising from the Maillard reaction between acetoin, 1,2-propanediol and hydrogen sulfide (furfural, furfuryl alcohol, 2- and 3-formylthiophenes, 2-acetylthiazole...). Some usual monoterpene hydrocarbons, citronellol, sesquiterpene hydrocarbons (beta-caryophyllene, daucene) and fused aromatic compounds (methyl- and dimethylnaphthalenes), in the Tricastin sample or by solvent extraction with pentane were also identified. Several aliphatic alcohols, acids, aldehydes and sulfides were also found. It is suggested that methoxylated benzenes and toluenes (mono, di, tri, and tetra derivatives) obtained by ether extraction, as well as 1,2,5,6-tetrahydropyridine contribute to the characteristic odor and aroma of black truffles. The quantitative composition varies depending on the separation method and thus it cannot be taken into account.
机译:来自法国南部两种不同地区的黑松露(块茎黑孢菌孢子)香气:i)三胞苷(Richerenches)和II)通过两种不同的提取方法研究了Alpes de Haute Provence(Simiane):a)使用戊烷和乙醚提取作为溶剂和B)固相微萃取(SPME)。通过GC / MS和保留指标识别了总共131种化合物。发现化学成分根据区域和提取方法不同。来自SPME方法获得的三胞菌素的黑松菌的有趣部分由丙酮蛋白,1,2-丙二醇和硫化氢(糠醛,糠醇,2--甲甲烯烯烯烯烯烯烯烯酮之间最有可能产生的杂环化合物,其杂循环化合物组成。 - 乙酰噻唑......)。还鉴定了一些常规的单萜烃,香橼,倍丙烯,Daucene烃(β-氰基,Daucene)和熔融芳族化合物(甲基和二甲基萘),在三胞苷样品中或用戊烷溶剂萃取的芳族化合物(甲基和二甲基萘)。还发现了几种脂族醇,酸,醛和硫化物。建议通过醚萃取获得的甲氧化苯和甲苯(单,二,三种,三种衍生物),以及1,2,5,6-四氢吡啶促进黑松露的特征气味和香气。定量组合物根据分离方法而变化,因此不能考虑它。

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