首页> 外文会议>International Conference on Advanced Ceramics and Composites >PHASE-BOUNDARY GROOVING AT SURFACES OF SOLID OXIDE FUEL CELL MATERIALS
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PHASE-BOUNDARY GROOVING AT SURFACES OF SOLID OXIDE FUEL CELL MATERIALS

机译:固体氧化物燃料电池材料表面的相 - 边界凹槽

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Thermal grooving was studied on the interfaces between two ceramic phases. Specimens of two-phase materials, lanthanum strontium manganite (LSM) and cerium oxide, 50-50 vol%, were prepared by mechanical milling and sintered at 1400 °C for 24 hrs. LSM and ceria are two important components for new generation solid oxide fuel cells (SOFC), and the boundary between these two and gas phase, forming a triple phase boundary (TPB), plays a significant role in the performance of a fuel cell. For the thermal grooving study, LSM-ceria specimens were polished and heat treated at 1400 °C for three annealing times. The phase boundaries were characterized and monitored by FESEM and AFM. It has been noticed that the formation and evolution of grooving at two-phase interfaces are similar to those observed in grain boundaries of single-phase systems. The preliminary data of the groove dimensions are presented.
机译:在两个陶瓷相之间的界面上研究了热槽。通过机械研磨制备两相材料,镧锶锰铁(LSM)和氧化铈,50-50体积%,在1400℃下烧结24小时。 LSM和Ceria是新一代固体氧化物燃料电池(SOFC)的两个重要组成部分,并且这两个和气相之间的边界形成三相边界(TPB),在燃料电池的性能中起着重要作用。对于热槽研究,抛光LSM-Ceria标本并在1400℃下热处理三次退火时间。通过FESEM和AFM表征和监测相界限。已经注意到,在两相界面处的凹槽的形成和演化类似于单相系统的晶界观察的那些。提出了凹槽尺寸的初步数据。

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