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RESEARCH OF THERMAL DECOMPOSITION OF DIANMINODINITROETHYLENE (FOX-7)

机译:Dianminodinitroethylante(Fox-7)热分解研究

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The results of performed studies allow the following conclusions: 1. DADNE crystallizes (at crystallization from formic acid, water acetone and water-acetone mixture) as four-faceted prisms; no differences in molecular structure of different types of DADNE crystals were found by FTIR; 2. At heating above +210° DADNE decomposes and a new explosive (DADNE-T) appears; 3. It has been demonstrated by results of thermal analysis and video record that DADNE does not melt in the temperature range up to +280° and has several polymorphous modifications (δ, δ, δ), with reversible transitions between modifications; 4. Presumably DADNE-T is a polymorphous modification ( ) stable in a temperature range from ~+20° to ~+270° .
机译:进行研究的结果允许以下结论:1。爸爸结晶(在甲酸,水丙酮和水 - 丙酮混合物中结晶)作为四面棱镜; FTIR发现不同类型的爸爸晶体的分子结构的差异;在加热以上+ 210°爸爸分数,出现新的炸药(DADNE-T); 3.通过热分析和视频记录的结果证明了DADNE在温度范围内不会熔化至+ 280°,并且具有多种多态性修改(Δ,Δ,δ),改动之间可逆转换; 4.大规模的DADNE-T是多晶体变形例()在〜+ 20°至〜+ 270°的温度范围内稳定。

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