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PLASTICIZATION of CELLULOSE NITRATES by MIXING LINEAR AZIDES and NITRAMINES

机译:通过混合线性叠氮化物和硝基胺的纤维素塑化

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摘要

The ability of apply a mix of linear nitramines and their derivatives as plasticizer of nitrates of cellulose (NC) is investigated. As plasticizer there has been a mix 2,4-dinitro-2,4,diazopentan, 1-azido-3,5-dinitro3,5-diazogexan and 1,5-diazido-3-nitro-3-azopentan. The scheme of the synthesis of plasticizer is described. There have been obtained the results on the basic physical and chemical properties of plasticizer. The thermal stability of the plasticizer, the rate of NC swelling into the plasticizer, the influence of concentration of the plasticizer to temperatures of relaxation transitions and mechanical properties plasticized NC are studied by means of the methods of the thermal analysis. It is shown, that this plasticizer is capable of plasticizing NC which has the high content of nitrogen. Plasticizer TA, in comparison to with nitroether plasticizers, possesses much higher plasticized effect.
机译:研究了将线性硝胺和它们的衍生物混合作为硝酸纤维素(NC)的增塑剂的能力。作为增塑剂,有2,4-二硝基-2,4,二齐顿,1-氮杂-3,5- DINITRO3,5-二氮代克纳和1,5-二氮杂-3-硝基-3-己戊烷。描述了增塑剂的合成方案。已经获得了增塑剂的基本物理和化学性质的结果。通过热分析方法研究了增塑剂的增塑剂的热稳定性,膨胀进入增塑剂的影响,增塑剂浓度和机械性能塑化的粘合性能。结果表明,该增塑剂能够塑化具有高含量的NC。与硝基醚增塑剂相比,增塑剂TA具有更高的增塑作用。

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