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Ion-Dipole Effects on the Binding in Cation-(pi) Complexes: Absolute Bond Dissociation Energies of Alkali Metal Cation-Methylated Aniline Complexes

机译：对阳离子（PI）配合物结合的离子偶极作用：碱金属阳离子 - 甲基化苯胺复合物的绝对粘合解离能

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Cation-(pi) interactions and their roles in structure determination, ion transport, and molecular recognition in biological systems as well as the possibility of using such interactions for separations and sensor applications has led to increasingly widespread studies of these interactions. In fundamental studies aimed at the detailed characterization of cation-(pi) interactions, we have employed guided ion beam tandem mass spectrometry techniques to examine a wide variety of cation-(pi) complexes to determine their absolute bond dissociation energies (BDEs).

机译：阳离子（PI）相互作用及其在生物系统中的结构测定，离子运输和分子识别中的作用以及使用这种相互作用的可能性导致了这些相互作用的越来越广泛的研究。在针对阳离子（PI）相互作用的详细表征的基本研究中，我们使用引导离子束串联质谱技术来检查各种阳离子（PI）复合物以确定它们的绝对粘合解离能（BDE）。

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《ASMS Conference on Mass Spectrometry and Allied Topics》|2006年||共2页
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Nuwan Hallowita; M. T. Rodgers;
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1. Influence of substituents on cation-π interactions. 3. Absolute binding energies of alkali metal cation-aniline complexes determined by threshold collision-induced dissociation and theoretical studies [J] . R. Amunugama, M. T. Rodgers International journal of mass spectrometry . 2003,第3期

机译：取代基对阳离子-π相互作用的影响。 3.阈值碰撞诱导离解确定的碱金属阳离子-苯胺络合物的绝对结合能和理论研究
2. Dipole Effects on Cation-π Interactions : Absolute Bond Dissociation Energies of Complexes of Alkali Metal Cations to N-methylaniline and N,N-dimethylaniline [J] . Nuwan Hallowita, Damon R. Carl, P. B. Armentrout The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2008,第35期

机译：偶极效应对阳离子-π相互作用的影响：碱金属阳离子与N-甲基苯胺和N，N-二甲基苯胺络合物的绝对键解离能
3. Dipole Effects on Cation-π Interactions : Absolute Bond Dissociation Energies of Complexes of Alkali Metal Cations to N-methylaniline and N,N-dimethylaniline [J] . Nuwan Hallowita, Damon R. Carl, P. B. Armentrout The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2008,第35期

机译：偶极效应对阳离子-π相互作用的影响：碱金属阳离子与N-甲基苯胺和N，N-二甲基苯胺络合物的绝对键解离能
4. Ion-Dipole Effects on the Binding in Cation-(pi) Complexes: Absolute Bond Dissociation Energies of Alkali Metal Cation-Methylated Aniline Complexes [C] . Nuwan Hallowita, M. T. Rodgers ASMS Conference on Mass Spectrometry and Allied Topics . 2006

机译：对阳离子（PI）配合物结合的离子偶极作用：碱金属阳离子 - 甲基化苯胺复合物的绝对粘合解离能
5. Experimental and theoretical studies of binding interactions in divalent transition metal cation-N-donor ligand complexes: Structures, sequential bond dissociation energies, mechanisms and energetics of collision-induced dissociation. [D] . Nose, Holliness. 2014

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6. Nucleophilicities of Lewis Bases B and Electrophilicities of Lewis Acids A Determined from the Dissociation Energies of Complexes B⋯A Involving Hydrogen Bonds Tetrel Bonds Pnictogen Bonds Chalcogen Bonds and Halogen Bonds [O] . Ibon Alkorta, Anthony C. Legon 2017

机译：Lewis碱B的亲核性和Lewis酸A的亲电性由涉及氢键Tetrel键Pnictogen键硫属元素键和卤素键的配合物B⋯A的解离能确定
7. Experimental And Theoretical Studies Of Binding Interactions In Divalent Transition Metal Cation-N-Donor Ligand Complexes: Structures, Sequential Bond Dissociation Energies, Mechanisms And Energetics Of Collision-Induced Dissociation [O] . Nose Holliness 2014

机译：二价过渡金属阳离子-N-供体配体配合物中结合相互作用的实验和理论研究：结构，顺序键离解能，碰撞诱导解离的机理和能量学
8. Binding of hydrocarbons and other extremely weak ligands to transition metal complexes that coordinate hydrogen: Investigation of cis-interactions and delocalized bonding involving sigma bonds [R] . Kubas, G. J., Eckert, J., Luo, X. L. 1997

机译：碳氢化合物和其他极弱配体与配位氢的过渡金属配合物的结合：顺式相互作用的研究和涉及σ键的离域键合

Ion-Dipole Effects on the Binding in Cation-(pi) Complexes: Absolute Bond Dissociation Energies of Alkali Metal Cation-Methylated Aniline Complexes

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