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首页> 外文会议>ASMS Conference on Mass Spectrometry and Allied Topics >Investigation for Gas-phase Fragmentation of N-phenyl ferrocene imine Derivatives Studied by Mass Spectrometry
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Investigation for Gas-phase Fragmentation of N-phenyl ferrocene imine Derivatives Studied by Mass Spectrometry

机译：质谱法研究了正苯基二甲基亚胺衍生物的气相破碎研究

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摘要

The fragmentation of a series of N-phenyl ferrocene imine derivatives was studied. The proton can transfer to the dissociative protonation sites and trigger the fragmentation. Major product ions resulted from electron transfer and proton transfer reactions via ion-neutral complexes, respectively. The intensities of ferrocinium cation were related to the electron affinities of the N-phenyl imine cations, whereas the formation of protonated ferrocene were controlled by the difference in proton affinity between the ferrocene and substituted isocyanobenzene within the complex.
机译：研究了一系列正苯基二茂铁亚胺衍生物的碎裂。质子可以转移到离防质子化位点并触发碎片。主要产物离子由电子转移和质子转移反应分别通过离子 - 中性复合物。二核素阳离子的强度与正苯基亚胺阳离子的电子亲和力有关，而质子化二茂茂的形成由配合物内的二茂铁和取代的异氰苯之间的质子亲和力的差异控制。

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