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Polymer and adhesive tape analysis by thermal desorption and pyrolysis combined with Direct Analysis in Real Time (DART) massspectrome

机译:聚合物和胶带通过热解吸和热解的分析和热解与直接分析实时(DART)质量分析

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Thermal desorption profiles for TDP/DART with the IonRocketshowed excellent reproducibility Thermal desorption permitted temperature-dependent separation of plasticizers and additives, resins, adhesives, and the base polymer The pyrolysis mass spectra allowed us to identify the base polymers and minimized suppression from additives with high proton affinities. Nonpolar polymers like polyethylene, polypropylene, polyvinyl chloride could be identified with the glass tee interface, but ion-molecule reactions cause a loss of polymer signal with the Vapurinterface. 3D plots provided a convenient means to visualize the total TDP/DART analysis Chemometricanalysis allowed us to identify individual manufacturers and brands for the duct tapes tested Deliberate contamination of the electrical tapes by exposing them to lab surfaces and human skin had minimal effect on the 3D plots for electrical tapes.
机译:用于TDP / DART的热解吸型材,具有离子插座的优异再现性热解吸允许的增塑剂和添加剂,树脂,粘合剂和基础聚合物的允许温度依赖性分离热解质谱允许我们鉴定基础聚合物并最小化来自添加剂的添加剂最小化抑制质子亲和力。诸如聚乙烯,聚氯乙烯等非极性聚合物可以用玻璃T界面鉴定,但离子分子反应导致具有vapur interface的聚合物信号的损失。 3D情节提供了一种方便的手段,可视化总TDP / DART分析化学分析,使我们可以识别所测试的管道胶带的各个制造商和品牌,通过将它们暴露于实验室表面,人体皮肤对3D地块具有最小的影响用于电动带。

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