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Gold Catalyzed 1,5- and 1,6-Propargylic Migrations of Ethers in Cycloisomerization of 1,6- and 1,7-Enynes.

机译：黄金催化1,5-和1,6-丙基偏移的醚在1,6-和1,7-兴奋剂中的环旋异构化中。

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Cycloisomerization of enynes has emerged as a powerful tool in the formation of complex carbon skeletons. 1,2- and 1,3-Propargylic migrations of acetates catalyzed by gold(I) are well known processes. We have now found that propargylic ethers undergo 1,5-migration in gold(I)-catalyzed cycloisomerization of 1,6-enynes. This transformation gives rise in a single step stereoselectively to tricyclic compounds related to the naturally occurring sesquiterpenes globulol (la), epiglobulol (lb), and halichonadin F (1c) (Scheme 1). Open allyl-gold carbocations were proposed as intermediates in this process.

机译：兴奋剂的环旋异构是在形成复杂碳骨架的强大工具中出现。由金（I）催化的乙酸盐的1,2-和1,3-丙基盖偏移是众所周知的方法。我们现在发现，在黄金（i）中进行了1,5-5-5-迁移的 - 催化了1,6- inynes的催化剂化。该转化将立体形成为立体选择性地升高到与天然存在的Sesquiterpenes球状酚（La），ePiglobulol（LB）和Halichonadin F（1C）（方案1）相关的三环化合物。在此过程中，提出了烯丙基金碳碳碳碳碳。

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《European Symposium on Organic Chemistry》|2009年||共1页
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Cesar R. Solorio-Alvarado; Eloisa Jimenez-Nunez; Mihai Raducan;
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中图分类有机化学;
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1. Mechanism of 1,3-Hydrogen Migration in a Gold Bicyclo[3.2.0]heptene Complex: The Role of Bronsted Acid in the Gold-Catalyzed Cycloisomerization of 7-Aryl-1,6-Enynes [J] . Brooner Rachel E. M., Robertson Bradley D., Widenhoefer Ross A. Organometallics . 2014,第22期

机译：双环[3.2.0]庚烯金复合物中1,3-氢迁移的机理：布朗斯台德酸在7-芳基-1,6-烯炔的金催化环异构中的作用
2. Mechanism of 1,3-Hydrogen Migration in a Gold Bicyclo[3.2.0]heptene Complex: The Role of Bronsted Acid in the Gold-Catalyzed Cycloisomerization of 7-Aryl-1,6-Enynes [J] . Brooner Rachel E. M., Robertson Bradley D., Widenhoefer Ross A. Organometallics . 2014,第22期

机译：双环[3.2.0]庚烯金复合物中1,3-氢迁移的机理：布朗斯台德酸在7-芳基-1,6-烯炔的金催化环异构中的作用
3. Gold-Catalyzed Cycloisomerization of 1,6-Diyne Esters to 1H-Cyclopenta[b]naphthalenes, cis-Cyclopenten-2-yl delta-Diketones, and Bicyclo[3.2.0]hepta-1,5-dienes [J] . Li Dan, Rao Weidong, Tay Guan Liang, The Journal of Organic Chemistry . 2014,第23期

机译：金催化的1，6-二炔酯的环异构化为1H-环戊[b]萘，顺-环戊-2-基δ-二酮和双环[3.2.0]庚-1,5-二烯
4. Gold Catalyzed 1,5- and 1,6-Propargylic Migrations of Ethers in Cycloisomerization of 1,6- and 1,7-Enynes. [C] . Cesar R. Solorio-Alvarado, Eloisa Jimenez-Nunez, Mihai Raducan European Symposium on Organic Chemistry . 2009

机译：黄金催化1,5-和1,6-丙基偏移的醚在1,6-和1,7-兴奋剂中的环旋异构化中。
5. Mechanistic insights into the role of silver in asymmetric gold(I) catalyzed cycloisomerization of 1,6-ene allenes [D] . Hulchanski, Allison J. 2013

机译：机械洞察银在不对称金（I）催化的1,6-烯丙二烯环异构化中的作用
6. Mechanistically Diverse Copper- Silver- and Gold- Catalyzed Acyloxy and Phosphatyloxy Migrations: Efficient Synthesis of Heterocycles via Cascade Migration/Cycloisomerization Approach [O] . Todd Schwier, Anna W. Sromek, Dahrika M. L. Yap, -1

机译：机械上多样的铜银和金催化的酰氧基和磷酰氧基迁移：通过级联迁移/环异构化方法高效合成杂环
7. Inside Cover: Ring Expansions Within the Gold-Catalyzed Cycloisomerization of O-Tethered 1,6-Enynes. Application to the Synthesis of Natural-Product-like Macrocycles (ChemCatChem 5/2013) [O] . Simonneau, Antoine, Harrak, Youssef, Jeanne-Julien, Louis, 2013

机译：内部封面：O系链的1,6-炔烃在金催化的环异构化过程中的环扩展。在类天然产物大环化合物的合成中的应用（ChemCatChem 5/2013）
8. Hydrolysis and Methanolysis of the Small Carboranes 1,5-C2B3H5, 1,6-C2B4H6,and 2,4-C2B5H7;The Preparation of the 1,3,5-Triborapentane Derivatives (RO)2BCH2B(OR)CH2B(OR)2, (R =Me or H). [R] . dobbie,robert c. wan, emma 1975

机译：小碳硼烷1,5-C2B3H5,1,6-C2B4H6和2,4-C2B5H7的水解和甲醇分解; 1,3,5-三硼烷戊烷衍生物（RO）2BCH2B（OR）CH2B（OR）2的制备，（R = me或H）。

Gold Catalyzed 1,5- and 1,6-Propargylic Migrations of Ethers in Cycloisomerization of 1,6- and 1,7-Enynes.

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