A novel gas-liquid-solid reactor based on monolith catalyst structure was developed for converting sugar alcohols to value-added chemicals such as propylene glycol. The structured catalyst was used intending to improve product selectivity. Testing at the pressure of 1,200 psig and 210°C with H2 to sorbitol molar ratio of 8.9 and a space velocity range from 0.15 to 5 hr"1 demonstrated that as high as 41 wt% of propylene glycol selectivity and 13 wt% ethylene glycol selectivity can be obtained. In addition, monolith catalysts gave higher C3/C2 ratio than that in the conventional trickle bed reactor with similar liquid hourly space velocities.
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机译:基于整体催化剂结构的新型气体 - 固体反应器用于将糖醇转化为增值化学品如丙二醇。使用结构化催化剂,用于改善产品选择性。在1,200psig的压力和210℃的压力下测试,山坡摩尔醇摩尔比为8.9和0.15至5hr“1的空速范围为0.15至5hr”1,表明高达41wt%的丙二醇选择性和13wt%乙二醇选择性可以获得。此外,单氧化硫催化剂在具有相似的液体小时间速度的常规流滴床反应器中得到较高的C 3 / C 2比。
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