Halophosphite Ligands for the Rhodium Catalyzed Low-Pressure Hydroformylation Reaction

机译：卤代磷酸盐配体用于铑催化的低压加氢甲酰化反应

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The discovery and use of fluorophosphites and chlorophosphites as trivalent phosphorus ligands in the rhodium catalyzed, low-pressure hydroformylation reaction are described. The hydroformylation reaction with halophosphite ligands has been demonstrated with terminal and internal olefins. For the hydroformylation of propylene, the linear to branched ratio of the butyraldehyde product shows a strong dependency on the ligand to rhodium molar ratios, the reaction temperature, and the carbon monoxide partial pressure.

机译：描述了荧光磷酸盐和氯核作为三价磷配体的发现和使用铑催化，低压加氢甲酰化反应中的三价磷配体。已用末端和内烯烃对与卤代磷酸盐配体进行加氢甲酰化反应。对于丙烯的加氢甲酰化，丁醛产物的分支比例表现出对铑摩尔比，反应温度和一氧化碳分级压力的强依赖性。

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《Organic Reactions Catalysis Society Conference》|2007年||共8页
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Thomas A. Puckette;
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中图分类化学动力学、催化作用;
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1. Chiral phosphine-phosphite ligands with a substituted ethane backbone. influence of conformational effects in rhodium-catalyzed asymmetric olefin hydrogenation and hydroformylation reactions [J] . Arribas I., Vargas S., Rubio M., Organometallics . 2010,第22期

机译：具有取代的乙烷主链的手性膦-亚磷酸酯配体。构象效应对铑催化的不对称烯烃加氢和加氢甲酰化反应的影响
2. Study of the effects of alkali metal salts on styrene hydroformylation reactions catalyzed by rhodium(I) complexes of bis(phosphite) ligands [J] . Owens SB, Gray GM Organometallics . 2008,第17期

机译：双（亚磷酸酯）配体铑（I）配合物催化碱金属盐对苯乙烯加氢甲酰化反应影响的研究
3. The use of a new ionic phosphite ligand in the hydroformylation catalyzed by rhodium complexes: Effect of reaction media [J] . Lyubimov S. E., Rastorguev E. A., Davankov V. A. Russian journal of physical chemistry, B. . 2014,第7期

机译：新的离子型亚磷酸酯配体在铑配合物催化的加氢甲酰化中的应用：反应介质的影响
4. Halophosphite Ligands for the Rhodium Catalyzed Low-Pressure Hydroformylation Reaction [C] . Thomas A. Puckette Organic Reactions Catalysis Society Conference . 2007

机译：卤代磷酸盐配体用于铑催化的低压加氢甲酰化反应
5. Rhodium-Catalyzed Asymmetric Hydroformylation of Alkenes Using Diazaphospholane Ligands and Application With Wittig Olefination. [D] . Wong, Gene W. 2012

机译：使用重氮磷烷配体进行铑催化的烯烃不对称加氢甲酰化反应，并在Wittig烯烃中进行应用。
6. Synthesis of Nixantphos Core-Functionalized Amphiphilic Nanoreactors and Application to Rhodium-Catalyzed Aqueous Biphasic 1-Octene Hydroformylation [O] . Ahmad Joumaa, Florence Gayet, Eduardo J. Garcia-Suarez, 2020

机译：Nixantphos核心功能性两亲纳米反应器的合成及其在铑催化的双相1-辛烯加氢甲酰化反应中的应用
7. N-Pyrrolylphosphines as ligands for highly regioselective rhodium-catalyzed 1-butene hydroformylation: effect of water on the reaction selectivity [O] . W. Alsalahi, R. Grzybek, A. M. Trzeciak 2017

机译：N-吡咯基膦作为高度区域选择性铑催化的1-丁烯加氢甲酰化的配体：水对反应选择性的影响
8. Hydroformylation Catalyzed by cis-Chelated Rhodium Complexes. Extension to Polymer-Anchored cis-Chelated Rhodium Catalysts. [R] . pittman,charles u. jr hirao, akira 1977

机译：顺式螯合铑配合物催化加氢甲酰化。扩展到聚合物锚定的顺式螯合铑催化剂。

Halophosphite Ligands for the Rhodium Catalyzed Low-Pressure Hydroformylation Reaction

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