首页> 外文会议>Annual Conference of Metallurgists >(595889) COMPLEX COPPER PYROMETALLURGY CHALLENGES AND OPPORTUNITIES - INTEGRATED EXPERIMENTAL PHASE EQUILIBRIA AND THERMODYNAMIC MODELLING RESEARCH AND IMPLEMENTATION
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(595889) COMPLEX COPPER PYROMETALLURGY CHALLENGES AND OPPORTUNITIES - INTEGRATED EXPERIMENTAL PHASE EQUILIBRIA AND THERMODYNAMIC MODELLING RESEARCH AND IMPLEMENTATION

机译:(595889)复杂的铜颤动冶金挑战与机遇 - 集成实验相平衡和热力学建模研究和实施

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The chemical compositions of copper feed streams are becoming increasingly complex following the growing demand for metals and corresponding shortages of primary sources. The optimisation of process conditions requires an accurate description of phase equilibria and thermodynamics. Integrated experimental and thermodynamic modelling research program on the characterisation of the complex, multi-component, multi-phase gas-slag-matte-speiss-metal-solids Cu_2O-PbO-ZnO-Al_2O_3-CaO-MgO-FeO-Fe_2O_3-SiO_2-S-(As-Bi-Ni-Sb-Sn-Ag-Au) system is being carried out to support companies undertaking the pyrometallurgical primary production and recycling of copper. The experiments involve high temperature equilibration in controlled gas atmospheres, rapid quenching and direct measurement of equilibrium phase compositions with quantitative microanalytical techniques, including electron probe X-ray microanalysis and Laser Ablation ICP-MS. The thermodynamic modelling is undertaken using FactSage computer package with advanced thermodynamic solution models. The continuing development of research methodologies has resulted in significant advances in research outcomes. Implementation of the results of these fundamental studies involves an ongoing collaboration of researchers and industry technologists. An overview of recent progress in research, implementation and applications in industrial practice are given in the paper.
机译:在对金属的需求不断增长的需求和主要来源的相应短缺之后,铜进料流的化学成分变得越来越复杂。过程条件的优化需要准确描述相平衡和热力学。综合实验性和热力学建模研究方案复合,多相,多相气渣 - 哑光 - 金属固体Cu_2O-PbO-ZnO-Al_2O_3-Cao-MgO-Feo-Fe_2O_3-SiO_2-正在进行S-(AS-BI-NI-SB-SN-AG-AG-AU)系统,以支持承担铜的Pyrome冶金初级生产和再循环的公司。该实验涉及控制气体环境的高温平衡,快速淬火和直接测量具有定量微扫描技术的平衡相组合物,包括电子探针X射线微分析和激光烧蚀ICP-MS。使用具有先进热力学解决方案模型的FactSage计算机包进行热力学建模。继续开发研究方法导致研究成果的重要进展。这些基本研究结果的实施涉及研究人员和行业技术人员的持续合作。本文给出了工业实践中最近研究,实施和应用进展的概述。

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