Formation of Diphosphine-Protected Gold Clusters: Cationic Cluster Formation from Digold Complexes as a Platform for Growth

机译：二膦保护金簇的形成：从Digold Compleases作为生长平台的阳离子簇形成

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Gold nanoclusters are projected for use in applications such as medical imaging, optics, catalysis, and targeted drug delivery. Because the properties of nanoclusters vary with core size and composition, it is anticipated that many applications will require monodisperse or nearly monodisperse clusters of specific compositions in order to achieve optimal efficacy. A problem for realizing this technology is that synthesis procedures that produce truly homogenous nanoclusters of chosen nuclearity are unknown. An atomistic level of understanding of the chemical processes governing cluster growth is unavailable. This study was designed to reveal the chemical reactions that govern early growth of phosphine-protected gold nanoclusters.

机译：预计金纳米纳米能器用于医学成像，光学，催化和靶向药物递送等应用。因为纳米能器的性质随核心尺寸和组成而变化，因此预期许多应用需要单分散或几乎单分散的特定组合物簇，以便实现最佳功效。实现这一技术的问题是产生真正均匀的核心纳米能量的合成程序是未知的。对群体增长的化学过程的原子理解水平不可用。本研究旨在揭示治理膦保护金纳米蛋白的早期生长的化学反应。

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《American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics》|2011年||共1页
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John Pettibone; Jeffrey W. Hudgens; Thomas Senftle; Denis E. Bergeron;
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1. Reaction network governing diphosphine-protected gold nanocluster formation from nascent cationic platforms [J] . John M. Pettibone, Jeffrey W. Hudgens Physical chemistry chemical physics: PCCP . 2012,第12期

机译：从新生的阳离子平台控制二膦保护的金纳米团簇形成的反应网络
2. Reaction network governing diphosphine-protected gold nanocluster formation from nascent cationic platforms [J] . John M. Pettibone, Jeffrey W. Hudgens Physical chemistry chemical physics: PCCP . 2012,第12期

机译：从新生的阳离子平台控制二膦保护的金纳米团簇形成的反应网络
3. Protein-Like Large Gold Clusters Based on the omega-Aminothiolate DMAET: Precision Thermal and Reaction Control Leading to Selective Formation of Cationic Gold Clusters in the Critical Size Range, n=130-144 Gold Atoms [J] . Hoque M. Mozammel, Dass Amala, Mayer Kathryn M., The journal of physical chemistry, C. Nanomaterials and interfaces . 2019,第23期

机译：基于OMEGA-氨基甲酸盐DMAET的蛋白质的大金簇：精密热量和反应控制，导致阳离子块的选择性形成临界尺寸范围，n = 130-144金原子
4. Formation of Diphosphine-Protected Gold Clusters: Cationic Cluster Formation from Digold Complexes as a Platform for Growth [C] . John Pettibone, Jeffrey W. Hudgens, Thomas Senftle, American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2011

机译：二膦保护金簇的形成：从Digold Compleases作为生长平台的阳离子簇形成
5. Supported metal carbonyl clusters and complexes: Formation, reactivity, and catalytic properties. [D] . Lobo, Rodrigo Javier. 2009

机译：负载的羰基金属簇和配合物：形成，反应性和催化性能。
6. Strong Electronic and Counterion Effects on Geminal Digold Formation and Reactivity as Revealed by Gold(I)–Aryl Model Complexes [O] . Dieter Weber, T. David Jones, Laura L. Adduci, -1

机译：黄金（I）-resall模型复合物揭示的初始电子和反压缩效应和造粒石上的模型和反应性
7. Protein-Like Large Gold Clusters Based on the Aminothiolate DMAET: Precision Thermal and Reaction Control Leading to Selective Formation of Cationic Gold Clusters in the Critical Size Range, n = 130144 Gold Atoms [O] . -1

机译：基于氨基甲酸酯DMAET的蛋白质的大金簇：精密热和反应控制，导致在临界尺寸范围内选择性地形成阳离子金簇，n = 130144金原子
8. Formation of Conducting Gold Films by Thermal Decomposition and Direct Patterning Using Electron Beam Lithography of the Gold Cluster Au55P((C6H5)3)12Cl6. [R] . Duchi, C. A., Kanskar, M., Wu, J. C., 1993

机译：利用金簇au55p（（C6H5）3）12Cl6的电子束光刻技术，通过热分解和直接图案化形成导电金膜。

Formation of Diphosphine-Protected Gold Clusters: Cationic Cluster Formation from Digold Complexes as a Platform for Growth

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