Chemical Ionization Reactions in a Field-Portable Membrane Introduction Mass Spectrometer for Selective, On-line Monitoring of Volatile and Semi-Volatile Organic Compounds

机译：用于选择性，在线监测挥发性和半挥发性有机化合物的特性膜引入质谱仪中的化学电离反应

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The extraction of hydrocarbons has the potential for the release of volatile and semi-volatile organic compounds (VOC/SVOCs) either as fugitive atmospheric emissions, process water releases or from accidental spills during handling or transportation. There is a need for methodology, which allows for real time, infield analysis that provides meaningful data without tedious or lengthy post possessing time to decouple potential isobaric interferences. The aim of this work was to utilize chemical ionization (CI) in a rugged, field portable, on -line membrane introduction mass spectrometer (MIMS) capable of both aqueous and atmospheric monitoring. A cylindrical ion trap mass spectrometer provides an ideal system to examine and apply CI / ion molecule reactions f or selective trace contaminant ionization and analysis.

机译：烃的提取具有释放挥发性和半挥发性有机化合物（VOC / SVOC）的可能性，也可以作为逃逸常压排放，工艺水释放或在处理或运输过程中脱毛。需要方法，它允许实时，infield分析提供有意义的数据，而没有繁琐或冗长的柱子，具有与潜在的异因干扰脱钩的时间。这项工作的目的是利用粗糙的田间便携式的化学电离（CI），直线膜引入质谱仪（MIMS）能够进行含水和大气监测。圆柱离子阱质谱仪提供理想的系统，用于检查和应用CI /离子分子反应F或选择性痕量污染物电离和分析。

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《American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics》|2012年||共2页
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Nicholas G. Davey; Ryan J. Bell; Christian Collin-Hansen; Erik T. Krogh; Christopher G. Gill;
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1. Single-sided membrane introduction mass spectrometry for on-line determination os semi-volatile organic compounds in air [J] . Leah S.Riter, Zoltan Takats, R.Graham Cooks The Analyst: The Analytical Journal of the Royal Society of Chemistry: A Monthly International Publication Dealing with All Branches of Analytical Chemistry . 2001,第11期

机译：在线测定空气中半挥发性有机化合物的单面膜引入质谱
2. A membrane introduction mass spectrometer utilizing ion-molecule reactions for the on-line speciation and quantitation of volatile organic molecules [J] . Davey Nicholas G., Bell Ryan J., Krogh Erik T., Rapid Communications in Mass Spectrometry: RCM . 2015,第23期

机译：膜引入质谱仪，利用离子分子反应对挥发性有机分子进行在线形态分析和定量
3. A new membrane inlet interface of a vacuum ultraviolet lamp ionization miniature mass spectrometer for on-line rapid measurement of volatile organic compounds in air [J] . Hou KY, Wang JD, Li HY Rapid Communications in Mass Spectrometry: RCM . 2007,第22期

机译：真空紫外灯电离微型质谱仪的新型膜入口接口，用于在线快速测量空气中的挥发性有机化合物
4. Chemical Ionization Reactions in a Field-Portable Membrane Introduction Mass Spectrometer for Selective, On-line Monitoring of Volatile and Semi-Volatile Organic Compounds [C] . Nicholas G. Davey, Ryan J. Bell, Christian Collin-Hansen, American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2012

机译：用于选择性，在线监测挥发性和半挥发性有机化合物的特性膜引入质谱仪中的化学电离反应
5. New Insights into Fossil Fuel Volatile Organic Compound Emissions and Chemistry using H3O+ and NO+ Chemical Ionization Mass Spectrometry. [D] . Koss, Abigail K. 2017

机译：使用H3O +和NO +化学电离质谱分析化石燃料中挥发性有机化合物的排放和化学的新见解。
6. Product ion distributions for the reactions of NO+ with some physiologically significant volatile organosulfur and organoselenium compounds obtained using a selective reagent ionization time-of-flight mass spectrometer [O] . Paweł Mochalski, Karl Unterkofler, Patrik Španěl, -1

机译：使用选择性试剂电离飞行时间质谱仪获得的NO +与一些生理上显着的挥发性有机硫和有机硒化合物反应的产物离子分布
7. A field portable membrane introduction mass spectrometer with in-line standard infusion and sample heat exchanger for real-time monitoring of volatile organic compounds in aqueous samples [O] . Morten R. Martinsen, Nicholas G. Davey, Ryan J. Bell, 2020

机译：具有在线标准输注和样品热交换器的现场便携式膜引入质谱仪，用于实时监测水性样品中的挥发性有机化合物

Chemical Ionization Reactions in a Field-Portable Membrane Introduction Mass Spectrometer for Selective, On-line Monitoring of Volatile and Semi-Volatile Organic Compounds

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