Gas-Phase Synthesis of Copper Carbene Complexes and Evaluation of their Structure and Reactivity

机译：气相合成铜卡宾络合物及其结构与反应性评价

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Copper (I) complexes easily react with betaine is solution. After losing CO2 and trimethyl amine by the application of CID energy, a copper carbene is formed and this carbene can react with alkenes presumably through a cyclopropanation catalytic cycle.

机译：铜（I）复合物容易与甜菜碱反应是溶液。通过施加CID能量输掉二氧化碳和三甲基胺后，形成铜基石，并且该咔啉可以通过环丙烷催化循环可以与烯烃反应。

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《American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics》|2013年||共1页
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Jamal Aldajaei; Scott Gronert;
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中图分类 TB994.5-53;
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1. Cationic copper(I) carbene complexes: Synthesis and structures of a tricoordinate copper(I) carbene water complex and a dicoordinate carbene complex [J] . López L.A., Barrio P., Borge J. Organometallics . 2012,第22期

机译：阳离子铜（I）卡宾配合物：三配位铜（I）卡宾水配合物和双配位卡宾配合物的合成与结构
2. Organic Synthesis via Transition Metal Complexes. 112. Reactivity Enhancement of Group VI Fischer Carbene Complexes by Copper and Rhodium Catalysts: Experimental proof of a Carbene Rhodium Complex as an Intermediate [J] . Inigo Gottker-Schnetmann, Rudolf Aumann, Klaus Bergander Organometallics . 2001,第16期

机译：通过过渡金属配合物的有机合成。 112.铜和铑催化剂增强第六族菲舍尔碳络合物的反应活性：碳铑铑络合物作为中间体的实验证明
3. Synthesis and structures of copper(I) complexes with phosphino- functionalized N-heterocyclic carbenes (NHCP) and bis-N-heterocyclic carbenes (Bis-NHC) [J] . Kühnel E., Shishkov I.V., Rominger F., Organometallics . 2012,第22期

机译：具有膦基官能化的N-杂环卡宾（NHCP）和双-N-杂环卡宾（Bis-NHC）的铜（I）配合物的合成和结构
4. Gas-Phase Synthesis of Copper Carbene Complexes and Evaluation of their Structure and Reactivity [C] . Jamal Aldajaei, Scott Gronert American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2013

机译：气相合成铜卡宾络合物及其结构与反应性评价
5. Metal complexes of tripodal N -heterocyclic carbene ligands: Synthesis, structure, bonding, and reactivity [D] . Hu, Xile 2004

机译：三脚架N-杂环卡宾配体的金属配合物：合成，结构，键合和反应性
6. Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes [O] . Jiwei Wang, Xiaoming Cao, Shichang Lv, -1

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7. Ruthenium(II) Porphyrin Quinoid Carbene Complexes: Synthesis, Crystal Structure, and Reactivity toward Carbene Transfer and Hydrogen Atom Transfer Reactions [O] . -1

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8. Synthesis and Reactivity of Backfluorinated NHC Carbene Complexes (Briefing Charts). [R] . Blanski, R., Grubbs, R. H. 2015

机译：反氟化NHC卡宾配合物的合成和反应性（简报图）。

Gas-Phase Synthesis of Copper Carbene Complexes and Evaluation of their Structure and Reactivity

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