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On-Line Mass Spectrometric Method for the Determination of the Primary Products of Fast Pyrolysis of Carbohydrates and Their Gas-Phase Manipulation

机译:在线质谱法测定碳水化合物快速热解的主要产物及其气相操纵

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摘要

APCI with Chloride and Ammonium Attachment Are Complementary Methods. Pyroprobe/APCI/MS/MS Setup Allows for High Throughput Analysis of Primary and Secondary Products of Pyrolysis. Fast Pyrolysis of Cellobiose and Cellulose Yields Unknown Products that Cannot Be Analyzed via GC. The Primary Products Quickly Polymerize. These Results Differ from Literature - Levoglucosan Was Proposed to be the Major Primary Product.
机译:含氯和铵附着的APCI是互补的方法。 Pyropobe / APCI / MS / MS设置允许对热解和二次产物的高通量分析进行热解。快速热解纤维素和纤维素产生未通过GC分析的未知产品。主要产品迅速聚合。这些结果与文献不同 - 左葡聚糖被提出为主要产品。

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