首页> 外文会议>DAE Solid State Physics Symposium >Comparison of structural and magnetic properties of Zn_xMg_(1.5-x)Mn_(0.5)FeO_4 and MgAl_xCr_xFe_(2-2x)O_4 spinel oxides
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Comparison of structural and magnetic properties of Zn_xMg_(1.5-x)Mn_(0.5)FeO_4 and MgAl_xCr_xFe_(2-2x)O_4 spinel oxides

机译:Zn_mg_(1.5-x)Mn_(0.5)Feo_4和Mgal_xcr_xfe_(2-2x)O_4尖晶石氧化物的结构和磁性的比较

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The spinel oxides Zn_xMg_(1.5-x)Mn_(0.5)FeO_4 (x = 0.0 to 0.6) and MgAl_xCr_xFe_(2-2x)O_4 (x = 0.0 to 0.6) abbreviated as ZMMFO and MACFO respectively, were synthesized by standard ceramic processing. The compositional purity of all the specimens was checked by EDAX technique. The X-ray diffractometry was employed to determine the lattice constants and distribution of cations in the interstitial voids. The initial decrease of cell edge parameter (a) for ZMMFO up to x = 0.2 and thereafter expected rise in the 'a' and the initial slower rate of reduction in the lattice constant for MACFO are explained as basic of cation occupancy. The magnetic ordering in both systems is explained by invoking statistical canting models. The compositional variation of magneton number (n_B) for ZMMFO could be very well explained by Localized canting of spin (LCS) model while Random canting of spin (RCS) model was used for MACFO system.
机译:通过标准陶瓷处理合成了缩写为ZMMFO和MacO的尖晶石氧化物Zn_XMG_(1.5-x)Mn_(0.5)FeO_4(x = 0.0至0.6)和MgAl_xcr_xfe_(2-2-2-2-2-2-2-2-2×)O_4(x = 0.0至0.6)。通过edax技术检查所有样本的组成纯度。使用X射线衍射法测定晶格常数和间质空隙中的阳离子分布。作为阳离子占用的基本占据占据占用率的基本解释,ZmMFO的初始降低至X = 0.2,然后在“A”和晶格常数的初始较慢速率上升的初始降低。通过调用统计累计模型,解释了两个系统中的磁性排序。通过局部化倾倒于旋转(LCS)模型,可以很好地解释ZMMFO的组成变化,而旋转(RCS)模型用于MACFO系统。

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