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SYNTHESIS OF CYCLOSAL-ACTIVATED GLYCOPYRANOSYL PHOSPHATES AND THEIR USE AS KEY BUILDING BLOCKS IN SYNTHESIS

机译：环塑活性甘吡喃糖基磷酸酯的合成及其用作合成中的关键构建块

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Glycosyl phosphate units are found in several bioconjugates serving versatile biological functions and are therefore major subjects of research. Our group developed a method for the efficient synthesis of phosphorylated biomolecules and (di)phosphate linked bioconjugates such as nucleoside di- and triphosphates, sugar nucleotides and dinucleoside oligophosphates. The cycloSal-approach uses an acceptor substituted cyclo Sal-phosphate triester as activated phosphate building block which is attacked by a nucleophile to give the desired conjugate (Scheme 1).

机译：糖基磷酸盐单元在多种生物缀合物中发现了多功能生物功能，因此是研究的主要科目。我们的组开发了一种有效合成磷酸化生物分子的方法和（二）磷酸盐连接的生物缀合物，例如核苷二磷酸，糖核苷酸和二核苷寡磷酸酯。环素 - 方法使用受体取代的环磷酸磷酸三酯作为活性磷酸盐构建块，其被亲核试剂攻击，得到所需的缀合物（方案1）。

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《International Carbohydrate Symposium》|2013年||共1页
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Huchting J.; Meier C.;
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中图分类天然化合物;
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机译：4-卤代3-氟-6-甲氧基喹啉的合成：合成抗生素的关键组成部分。
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4. SYNTHESIS OF CYCLOSAL-ACTIVATED GLYCOPYRANOSYL PHOSPHATES AND THEIR USE AS KEY BUILDING BLOCKS IN SYNTHESIS [C] . Huchting J., Meier C. International Carbohydrate Symposium . 2013

机译：环塑活性甘吡喃糖基磷酸酯的合成及其用作合成中的关键构建块
5. Synthesis of 4'-O-glycopyranosyl paromomycin aminoglycoside antibiotics: Influence of the glycoside on antiribosomal, antibacterial activity and utilization of electrospray ionization mass spectrometry to evaluate reactivity of glycosyl phosphate. [D] . Chen, Weiwei. 2014

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SYNTHESIS OF CYCLOSAL-ACTIVATED GLYCOPYRANOSYL PHOSPHATES AND THEIR USE AS KEY BUILDING BLOCKS IN SYNTHESIS

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