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Effect of Unmodified and Modified Epoxidized Soyabean Oils on Properties of Black-NBR Compounds and Black-NBR Vulcanizates

机译:未改性和改性环氧化大豆油对黑NBR化合物和黑NBR硫化物性能的影响

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In this study, feasibility of using epoxidized soyabean oil (ESO) and N-pheny-p-phenylenediamine modified ESO (pA-m-ESO) as rubber processing oil in a formulation of carbonblack filled acrylonitriie butadiene rubber (NBR) compound was investigated. It is seen that properties of the NBR compounds (i.e., total mixing energy, dump temperature, Mooney viscosity and curing characteristic) with using the DOP and the ESO were comparable, unlike the compound with using the pA-m-ESO. However, after vulcanization the NBR vulcanizate with using the DOP showed superior modulus, tensile strength and hardness than those of the others. This is due to interaction between the processing oil and the NBR phases as well as reinforcing effect of the carbon black on NBR molecules. However, no differences of dispersion and distribution of carbon black in the NBR vulcanizates with varying types of processing oil were observed.
机译:在本研究中,研究了使用环氧化大豆(ESO)和N-苯基 -P-苯二胺改性ESO(PA-M-ESO)作为橡胶加工油的可行性被研究作为碳纤维填充丙烯腈丁二烯橡胶(NBR)化合物的制剂中的橡胶加工油。可以看出,与使用PA-M-ESO的化合物不同,使用DOP和ESO的NBR化合物(即,总混合能量,倾卸温度,门尼粘度和固化特性的性质相当。然而,在硫化后,使用DOP的NBR硫化酸盐显示出优异的模量,拉伸强度和硬度比其他模量。这是由于加工油和NBR相之间的相互作用以及炭黑在NBR分子上的增强效果。然而,观察到NBR硫化橡胶中的炭黑的分散和分布没有不同类型的加工油的差异。

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