Synthesis of allyl-functionalized polymers via selective reversible addition-fragmentation chain transfer (RAFT) polymerization

机译：通过选择性可逆添加 - 碎片链转移（筏）聚合来合成烯丙基官能化聚合物

获取原文

页面导航

摘要
著录项
相似文献
相关主题

摘要

Allyl-functionalized copolymers with well-defined structure have been successfully prepared via selective reversible addition-fragmentation chain transfer (RAFT) copolymerization of styrene and allyl methacrylate possessing a higher reactive methacrylate and a lower reactive allyl. By employing a fast RAFT equilibrium, the polymerization for AMA completely occurred in methacrylate double bonds, whereas allyl double bonds remained intact and were introduced into the side-chains. GPC and ~1H NMR analyses have confirmed the high chain-end functionality of the resultant copolymer.

机译：通过具有较高反应性甲基丙烯酸酯和低反应性烯丙基的苯乙烯和烯丙基甲基丙烯酸酯的选择性可逆添加 - 碎片链转移（筏）共聚成功制备具有明确定义的结构的烯丙基官能化共聚物。通过采用快速筏平衡，AMA的聚合完全发生在甲基丙烯酸酯双键中，而烯丙基双键保持完整并将其引入侧链。 GPC和〜1H NMR分析证实了所得共聚物的高链末端官能团。

著录项

来源
《China International Nanoscience and Technology Symposium》|2014年||共4页
会议地点
作者
Zhanjun Liu; Mingfei Zhao; Zhengang Wu; Gang Han;
展开▼
作者单位

展开▼
会议组织
原文格式 PDF
正文语种
中图分类 TB383-53;
关键词
Reversible addition-fragmentation chain transfer (RAFT); Allyl methacrylate; Styrene; Random copolymerization;

机译：可逆添加 - 碎片链转移（筏）;烯丙基甲基丙烯酸酯;苯乙烯;无规共聚;

相似文献

外文文献
中文文献
专利

1. Synthesis and characterization of well-defined polymer brushes grafted from silicon surface via surface reversible addition-fragmentation chain transfer (RAFT) polymerization [J] . Kun Yuan, Zhi-Feng Li, Ling-Ling LU, Materials Letters . 2007,第10期

机译：通过表面可逆加成-断裂链转移（RAFT）聚合从硅表面接枝的定义明确的聚合物刷的合成和表征
2. Facile synthesis of comb, star, and graft polymers via reversible addition-fragmentation chain transfer (RAFT) polymerization [J] . Quinn JF., Chaplin RP., Davis TP. Journal of Polymer Science, Part A. Polymer Chemistry . 2002,第17期

机译：通过可逆加成-断裂链转移（RAFT）聚合轻松合成梳状，星形和接枝聚合物
3. Synthesis of Stimuli Responsive Graft Triblock Polymers via Combination of Reversible Addition-Fragmentation Chain Transfer Polymerization and Ring Opening Polymerization [J] . Chengun Wu, Anguo Ying, Shibin Ren Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry . 2013,第6期

机译：通过可逆加成-断裂链转移聚合和开环聚合的组合来合成刺激响应性接枝三嵌段聚合物
4. Synthesis of allyl-functionalized polymers via selective reversible addition-fragmentation chain transfer (RAFT) polymerization [C] . Zhanjun Liu, Mingfei Zhao, Zhengang Wu, China International Nanoscience and Technology Symposium . 2014

机译：通过选择性可逆添加 - 碎片链转移（筏）聚合来合成烯丙基官能化聚合物
5. Functional and complex polymer architectures: Macromolecular design via reversible addition-fragmentation chain transfer (RAFT) polymerization. [D] . Patton, Derek Lee. 2006

机译：功能和复杂的聚合物体系结构：通过可逆的加成-断裂链转移（RAFT）聚合进行大分子设计。
6. Surface-confined aqueous reversible addition-fragmentation chain transfer (SCARAFT) polymerization method for preparation of coated capillary leads to over 10 000 peptides identified from 25 ng HeLa digest by using capillary zone electrophoresis-tandem mass spectrometry [O] . Zhenbin Zhang, Elizabeth H. Peuchen, Norman J. Dovichi -1

机译：表面受限的水性可逆加成-断裂链转移（SCARAFT）聚合方法用于制备包覆的毛细管导致使用毛细管区带电泳-串联质谱分析法从25 ng HeLa酶切物中鉴定出1万多个肽段
7. Graft Polymerization: Grafting Poly(styrene) from Cellulose via Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization [O] . -1

机译：接枝聚合：通过可逆添加 - 碎片链转移（筏）聚合从纤维素接枝聚（苯乙烯）
8. Reversible Addition-Fragmentation Chain Transfer (RAFT) Copolymerization of Fluoroalkyl Polyhedral Oligomeric Silsesquioxane (F-POSS) Macromers (Postprint). [R] . Ramirez, S. M., Diaz, Y. J., Sahagun, C. M., 2013

机译：可逆加成 - 断裂链转移（RaFT）共聚合氟烷基多面体低聚倍半硅氧烷（F-pOss）大分子单体（postprint）。

Synthesis of allyl-functionalized polymers via selective reversible addition-fragmentation chain transfer (RAFT) polymerization

摘要

著录项

相似文献

相关主题

期刊订阅