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Polymer Suspensions - New Alternatives in Oilfield Chemistry

机译:聚合物悬浮液 - 油田化学的新替代品

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The different polymers are available as concentrated solutions, gels, crushed powders, beads, and partially pre-crosslinked solid microgels. Applying special dispensers and slicing units with sophisticated apparatus for filtering and relaxation storage, all solid polymers often cause serious formation damage due to their poor and slow solubility in water. Therefore, searching such formulations, which eliminate the mentioned drawbacks, may contribute significantly to improvement of polymer technologies. One of the possible options is the application of "liquid" polymer. The "liquid" polymer is a stabilized suspension of bead-like polymers in water-miscible solvent with active content of 40-45%. The polymer beads are monodispersed and have narrow size distribution (<1 mm). Usually tenside mixtures are used to stabilize these dispersions. The laboratory studies focused on laser particle sizing, dissolution kinetics, colloid chemical, Theological, and flow properties in porous media (sandstone) Based on the experimental findings, it was found that "liquid" polymers readily and rapidly dissolve in water (within less than 2 h), the solutions are free of microgels and mechanical entrapment was minimal even in low permeable (<25 mD) sandstone cores. In addition, they decrease the surface tension to 30-35 mN/m, the interfacial tension lowering was also min. one order of magnitude, and they proved to be compatible with other chemicals. It was also proved that the rheological and flow properties were identical or very similar to those data obtamed by conventional solid polymers having similar structure. The extra beneficial properties of "liquid" polymers in all oilfield chemical applications may significantly contribute to improvement of polymer-based technologies; meanwhile the surface facilities can be simplified, or completely eliminated (e.g. the "liquid" polymer can be directly injected to the wellhead in "smart" water flooding). In addition, the chemical cost of commercial products is practically the same as of the solid polymers Earlier the "liquid" polymer was successfully applied in water shutoff and conformance treatments in Oman using silicate/polymer gel. and recently for water shutoff treatments in Hungary using silicate/polymer solution with nanoparticle (silica) fillers. Based on the laboratory studies and successful filed pilots, the "liquid" polymers may open new vistas in all oilfield applications.
机译:不同的聚合物可作为浓缩溶液,凝胶,碎粉末,珠子和部分预交联的固体微凝胶。使用特殊分配器和切片单元进行复杂的过滤和放松储存,所有固体聚合物常常引起严重的形成损坏,因为它们的差和缓慢溶解度。因此,搜索消除提到的缺点的这种配方可以显着促进聚合物技术的改进。其中一种可能的选择是“液体”聚合物的应用。 “液体”聚合物是在水溶性溶剂中稳定的珠状聚合物的稳定悬浮液,其活性含量为40-45%。聚合物珠粒是单分散的并且具有窄尺寸分布(<1mm)。通常使用抗抗体混合物来稳定这些分散体。基于实验发现,实验室研究专注于激光粒度尺寸,溶解动力学,胶体化学,神经介质(砂岩)中的神学和流动性质,发现“液体”聚合物容易溶解在水中(小于2小时),溶液不含微凝胶,即使在低渗(<25 md)砂岩芯中,机械夹带也很小。此外,它们将表面张力降低至30-35mn / m,界面张力降低也是分钟。一个数量级,他们证明与其他化学品相容。还证实了流变和流动性质与具有类似结构的常规固体聚合物所履离的那些数据相同或非常相似。所有油田化学应用中的“液体”聚合物的额外有益特性可能会显着促进基于聚合物的技术;同时,可以简化表面设施,或者完全消除(例如,“液体”聚合物可以直接注入到“智能”水洪水中的井口中。此外,商业产品的化学成本实际上与固体聚合物的实际相同,使用硅酸盐/聚合物凝胶成功地应用于阿曼的水截止和一致性处理中的“液体”聚合物。最近利用含有硅酸盐/聚合物溶液(二氧化硅)填料的匈牙利的水关闭治疗。基于实验室研究和成功的备用飞行员,“液体”聚合物可以在所有油田应用中打开新的Vistas。

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