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Synthesis and Characterization of Biomimetic Strontium Substituted Carbonated Calcium-Deficient Hydroxyapatite Deposited on Carbon Fiber Cloths

机译:碳纤维布上沉积碳纤维布料碳酸锶取代碳酸钙缺陷羟基磷灰石的合成与表征

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Calcium phosphate (CaP) ceramics, e.g. hydroxyapatite Ca_(10)(PO_4)_6(OH)_2 (HAP) and tricalcium phosphate Ca_3(PO_4)_2 (TCP), are widely employed in the field of bone tissue engineering due to their controlled biodegradability and excellent biocompatibility. In the present study, the chemical composition, microtexture and structure of CaP deposits on carbon fiber cloths (CFC) are investigated. Coatings of CaP or strontium-substituted calcium phosphate (Sr-CaP) on CFC are obtained by sono-electrodeposition process using cathodic polarization. At constant potential, the deposits consist in a biomimetic carbonated calcium-deficient hydroxyapatite (CaD-HAP), having a plate-like morphology with the possibility to control the Sr~(2+) incorporation. In orthopaedic field, CaP or Sr-CaP coated carbon fiber cloths offer new promising bioceramic materials for bone repair and regeneration.
机译:磷酸钙(帽)陶瓷,例如陶瓷。羟基磷灰石CA_(10)(PO_4)_6(OH)_2(HAP)和磷酸三钙CA_3(PO_4)_2(TCP),由于其受控的生物降解性和优异的生物相容性,骨组织工程领域被广泛使用。在本研究中,研究了碳纤维布(CFC)上帽沉积物(CFC)的化学成分,微节纹理和结构。 CFC上的帽或锶取代的磷酸钙(SR-Cap)涂层是通过使用阴极极化的超声电沉积工艺获得的。在恒定的电位下,沉积物在染色碳酸钙缺乏羟基磷灰石(CAD-HAP)中,具有控制SR〜(2+)掺入的可能性。在骨科领域,帽或SR帽涂层碳纤维布为骨修复和再生提供了新的有希望的生物陶瓷材料。

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