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Sorption behavior of dodecylbenzene sulfonic acid on humic acids fromMollisol and Alluvial soils

机译:二甲基苯磺酸对来自莫酚和冲积土壤腐殖酸的吸附行为

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In this paper the sorption behavior of DBSA on two different types of soil humic acids (HAs) was investigated and the mechanisms of their interactions were further discussed. HAs were extracted and isolated from two representative soils, i.e., Mollisol soil and Alluvial soil. HAs sorbed by DBSA were measured by UV-vis and studied using the batch equilibrium method. Furthermore, the sorption complexes were analyzed by the means of elemental analysis, micro-Fourier transform infrared spectroscopy (FTIR), solid-state 13C nuclear magnetic resonance (NMR) spectroscopy and electron spin resonance spectra (ESR) in order to probe the sorption mechanisms. The sorption kinetics were relatively slow and the sorption equilibrium could be reached within 48 h. The sorption capacity of the Alluvial soil HA (AHA) was greater than that of the Mollisol soil HA (MHA). The maximum DBSA adsorption capacity on the AHA and the MHA was 115.01 mg/g and 112.17 mg/g, respectively.
机译:本文研究了DBSA对两种不同类型土壤腐殖酸(具有)的吸附行为,并进一步讨论了它们的相互作用的机制。已从两种代表性的土壤中提取和分离,即Mollisol土壤和冲积土壤。通过UV-Vis测量了DBSA并使用批量平衡方法测量的已经过量测量。此外,通过元素分析,微傅里叶变换红外光谱(FTIR),固态13C核磁共振(NMR)光谱和电子自旋共振光谱(ESR)来分析吸附复合物,以便探测吸附机制。吸附动力学相对较慢,可以在48小时内达到吸附平衡。冲积土壤HA(AHA)的吸附能力大于Mollisol土壤HA(MHA)的吸附能力。 AHA和MHA上的最大DBSA吸附容量分别为115.01mg / g和112.17mg / g。

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